(4-[p-[N-(4-(9-carbazole))butyl-N-phenyl]aniline]-6-phenyl-2,2'-bipyridine)chloridoplatinum(II) | 1236350-51-8

• 英文名称: (4-[p-[N-(4-(9-carbazole))butyl-N-phenyl]aniline]-6-phenyl-2,2'-bipyridine)chloridoplatinum(II)
• 英文别名: [(4-(p-[N-(4-(9-carbazole)butyl)-N-phenyl]amino)-6-phenyl-2,2'-bipyridine-H)PtCl]
• CAS: 1236350-51-8
• 化学式: C₄₄H₃₅ClN₄Pt
• 分子量: 850.322
• InChiKey: LNKMFXAFNQYIKE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (4-[p-[N-(4-(9-carbazole))butyl-N-phenyl]aniline]-6-phenyl-2,2'-bipyridine)chloridoplatinum(II) 、 苯乙炔 在 CuI 、 Et₃N 作用下， 以 二氯甲烷 为溶剂， 以87%的产率得到[(4-(p-[N-(4-(9-carbazole)butyl)-N-phenyl]amino)-6-phenyl-2,2'-bipyridine-H)Pt(C2(C6H5))]
  参考文献：
  名称：

  Electrochromic films with high optical contrast prepared by oxidative electropolymerization of a novel multi-functionalized cyclometalating ligand and its neutral-charged Pt(II) complexes

  摘要：

  A novel multi-functionalized cyclometalating ligand (HL) and its two neutral-charged Pt(II) complexes, i.e., [(L)PtCl] (C1) and [(L)Pt(C equivalent to CC6H5)] (C2) (HL=4-{p-[N-(4-(9-carbazole))butyl-N-phenyl]anilino}-6-phenyl-2,2'-bipyridine), have been successfully synthesized and verified by H-1 NMR, C-13 NMR, elemental analysis and/or X-ray crystallography. The introduction of the electron-donating arylamino unit at the 4-position of the electron-withdrawing 6-phenyl-2,2'-bipyridine ligand forms the D-A system, resulting in the enhanced (MLCT)-M-1 bands in the absorption spectra and intense orange emissions in the PL spectra of C1 and C2. The carbazole units grafted through alkyl chain in HL, C1 and C2 electrochemically trigger the efficient cross-linking reaction to form polymer films, which have been characterized by AC impedance, SEM and spectroelectrochemistry. Each of the poly-HL and poly-C1 films exhibits reversible oxidation with significant color change having a high contrast ratio (81.8% for poly-HL film and 67.3% for poly-C1 film), a reasonable coloration response time (6.3 s for poly-HL film and 3.1 s for poly-C1 film) and a comparable coloration efficiency (158C(-1) cm(2) for poly-HL film and 132C(-1) cm(2) for poly-C1 film) that can be switched by modulation of the applied potential. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2011.11.083
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 4-[p-[N-(4-(9-carbazole))butyl-N-phenyl]aniline]-6-phenyl-2,2'-bipyridine 以 溶剂黄146 为溶剂， 以82.4%的产率得到(4-[p-[N-(4-(9-carbazole))butyl-N-phenyl]aniline]-6-phenyl-2,2'-bipyridine)chloridoplatinum(II)
  参考文献：
  名称：

  具有多功能环金属化配体的新型 Pt(II) 配合物的合成、晶体结构和光物理性质

  摘要：

  一种新型 Pt(II) 配合物 [(L)PtCl] (HL = 4-{4p-[N-(4-(9-carbazole))butyl-N-phenyl] aniline}-6-phenyl-2,2' -联吡啶）已合成并通过 H-1 NMR、元素分析和 X 射线晶体学验证。该晶体（C44H35N4ClPt，Mr = 850.30）属于单斜晶系，空间群P2（1）/c，a = 21.864（6），b = 9.306（3），c = 17.240（5）埃，β = 96.483（ 6)度，Z = 4，V = 3485.3(16)埃(3)，DC = 1.620 g/cm(3)，mu(Mo-K alpha) = 4.141 mm(-1)，F(000) = 1688 , R-1 = 0.0591, wR(2) = 0.0976。Pt 原子的坐标几何是一个扭曲的方形平面配置。复杂的分子通过弱的 pi-pi 相互作用以头对尾的方式沿着

  DOI：

  10.1016/j.inoche.2010.02.016