| 151757-52-7

• CAS: 151757-52-7
• 化学式: C₄₆H₃₈ClNOP₂Ru
• 分子量: 819.284
• InChiKey: IRNFETAMQILYLO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 4-甲苯基乙炔 以 1,2-二氯乙烷 为溶剂， 以58%的产率得到
  参考文献：
  名称：

  Synthesis of butenynylruthenium complexes from hydrido, alkenyl, or alkynyl complexes

  摘要：

  The reaction Of Ru(CO)ClH(PPh3)3 with 1-alkynes in 1,2-dichloroethane under reflux conditions provides the coordinatively unsaturated butenynyl complexes [Ru{C(C=CR)=CHR}(CO)Cl(PPh3)2] in good yield. These and related butenynyl complexes were also prepared by starting from the corresponding alkenyl- or alkynylruthenium complexes. Hydrogenolysis of [Ru{C(C=CPh)=CHPh}(CO)Cl(PPh3)2] in the presence of pyridine gave (Z)-1,4-diphenylbutenyne and Ru(CO)ClH(py)(PPh3)2.

  DOI：

  10.1021/om00034a070
• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 喹啉 以 乙醇 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Synthesis of butenynylruthenium complexes from hydrido, alkenyl, or alkynyl complexes

  摘要：

  The reaction Of Ru(CO)ClH(PPh3)3 with 1-alkynes in 1,2-dichloroethane under reflux conditions provides the coordinatively unsaturated butenynyl complexes [Ru{C(C=CR)=CHR}(CO)Cl(PPh3)2] in good yield. These and related butenynyl complexes were also prepared by starting from the corresponding alkenyl- or alkynylruthenium complexes. Hydrogenolysis of [Ru{C(C=CPh)=CHPh}(CO)Cl(PPh3)2] in the presence of pyridine gave (Z)-1,4-diphenylbutenyne and Ru(CO)ClH(py)(PPh3)2.

  DOI：

  10.1021/om00034a070