(η(5)-C5Ph4(p-tolyl))Fe(CO)2H | 155477-12-6

• 英文名称: (η(5)-C5Ph4(p-tolyl))Fe(CO)2H
• CAS: 155477-12-6
• 化学式: C₃₈H₂₈FeO₂
• 分子量: 572.486
• InChiKey: XMYNQZNSAJJRDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(5)-C5Ph4(p-tolyl))Fe(CO)2H 在 三苯基氯甲烷 、 锌 作用下， 以 苯 为溶剂， 以78%的产率得到[(η(5)-C5Ph4(p-tolyl))Fe(CO)2]2
  参考文献：
  名称：

  The 18-Electron, Metal−Metal-Bonded Dimers [η⁵-C₅Ph₅Fe(CO)₂]₂ and [η⁵-C₅Ph₄(p-tolyl)Fe(CO)₂]₂:  Their Proclivity To Undergo Spontaneous, Thermal Homolysis to the Corresponding 17-Electron Monomers

  摘要：

  The known compound [Cp double dagger Fe(CO)(2)](2) and the new, more soluble [Cp double dagger Fe(CO)(2)](2) (Cp double dagger = eta(5)-C(5)Ph(5); Cp double dagger = eta(5)-C(5)Ph(4)(p-tolyl)) are prepared via a new, very effective route involving hydridic hydrogen atom abstraction from the hydrides, Cp double dagger Fe(CO)(2)H and Cp double dagger Fe(CO)(2)H, by the trityl radical. The dimers dissociate thermally to the corresponding 17-electron monomers, Cp double dagger-Fe(CO)(2) and Cp double dagger Fe(CO)(2), which probably assume ''planar'' (C-2v) structures with OC-Fe-CO bond angles of similar to 90 degrees.

  DOI：

  10.1021/om960323x
• 作为产物：
  描述：

  bromodicarbonyl{2,3,4,5-tetraphenyl-1-(p-tolyl)cyclopenta-2,4-dienyl}iron(II) 、 sodium tetrahydroborate 以 四氢呋喃 、 水 为溶剂， 以82%的产率得到(η(5)-C5Ph4(p-tolyl))Fe(CO)2H
  参考文献：
  名称：

  The 18-Electron, Metal−Metal-Bonded Dimers [η⁵-C₅Ph₅Fe(CO)₂]₂ and [η⁵-C₅Ph₄(p-tolyl)Fe(CO)₂]₂:  Their Proclivity To Undergo Spontaneous, Thermal Homolysis to the Corresponding 17-Electron Monomers

  摘要：

  The known compound [Cp double dagger Fe(CO)(2)](2) and the new, more soluble [Cp double dagger Fe(CO)(2)](2) (Cp double dagger = eta(5)-C(5)Ph(5); Cp double dagger = eta(5)-C(5)Ph(4)(p-tolyl)) are prepared via a new, very effective route involving hydridic hydrogen atom abstraction from the hydrides, Cp double dagger Fe(CO)(2)H and Cp double dagger Fe(CO)(2)H, by the trityl radical. The dimers dissociate thermally to the corresponding 17-electron monomers, Cp double dagger-Fe(CO)(2) and Cp double dagger Fe(CO)(2), which probably assume ''planar'' (C-2v) structures with OC-Fe-CO bond angles of similar to 90 degrees.

  DOI：

  10.1021/om960323x

文献信息

• Kuksis, Inga; Baird, Michael C., Organometallics, 1994, vol. 13, # 5, p. 1551 - 1553
  作者：Kuksis, Inga、Baird, Michael C.

  DOI：——

  日期：——