5-[3-(2-benzthiazolethiol)butoxyphenyl]-10,15,20-tri(4-methylphenyl)porphyrinatoiron(III) chloride | 355134-23-5

• 英文名称: 5-[3-(2-benzthiazolethiol)butoxyphenyl]-10,15,20-tri(4-methylphenyl)porphyrinatoiron(III) chloride
• CAS: 355134-23-5
• 化学式: C₅₈H₄₅ClFeN₅OS₂
• 分子量: 983.46
• InChiKey: YARXHZXZJHXHJI-BAKOTOFFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  咪唑 、 5-[3-(2-benzthiazolethiol)butoxyphenyl]-10,15,20-tri(4-methylphenyl)porphyrinatoiron(III) chloride 以 氯仿 为溶剂， 生成 bis(imidazole)(5-[3-(2-benzthiazolethiol)butoxyphenyl]-10,15,20-tri(4-methylphenyl)porphyrinatoiron(III)) chloride
  参考文献：
  名称：

  SYNTHESIS, CHARACTERIZATION, AND CATALYTIC STUDIES OF NEW BENZIMIDAZOLE-, BENZTHIAZOLE-, AND BENZAZOLE-LINKED IRON(III) PORPHYRINS

  摘要：

  Three new tailed iron(III) porphyrin complexes, 5-[3-(2-benzimidazolethiol)butoxyphenyl]-10,15,20-tri(4-methylphenyl) porphyrinatoiron(III) chloride [m-Bz-Im(BO)Ph(4-MePh)(3)PFe(III)Cl] (P = porphyrin), 5-[3-(2-benzthiazolethiol)butoxyphenyl] 10,15,20-tri(4-methylphenyl)porphyrinatoiron(III) chloride [m-BzTa(Bo)Ph(4-MePh)(3)PFe(III)Cl], and 5-[3-(2-benzazolethiol)butoxyphenyl]-10,15,20-tri(4-methylphenyl)porphyrinatoiron (III) chloride [m-BzAz(BO)Ph(4-MePh)(3)PFe(III)Cl], have been prepared and characterized by elemental analyses,H-1-NMR, IR, UV-vis, mass, ESR, and magnetic circular dichroism spectra. The catalytic activities of these complexes in the hydroxylation of cyclohexane with O-2 as the oxygen source were investigated under mild conditions. The results indicated that these complexes had higher catalytic activity than tetra(4-methylphenyl)pophyrinatoiron(LII) chloride [(4-MePh)(4)PFe(LII)Cl] due to the coordination and stabilization of the terminal groups benzimidazole (BzIm(-)), benzthiazole (BzTa(-)), and benzazole (BzAz(-)) to the iron centers.

  DOI：

  10.1081/sim-100001929