| 86308-25-0

• CAS: 86308-25-0
• 化学式: C₇₄H₄₂Fe₂N₁₈O
• 分子量: 1310.96
• InChiKey: CABANYKVUDZUQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 [(phthalocyanine)Fe]₂O
  参考文献：
  名称：

  Ercolani, Claudio; Gardini, Marcello; Murray, Keith S., Inorganic Chemistry, 1987, vol. 26, # 21, p. 3539 - 3543

  摘要：

  DOI：
• 作为产物：
  描述：

  吡啶 、 [(phthalocyanine)Fe]₂O 以 吡啶 为溶剂， 生成
  参考文献：
  名称：

  Ercolani, Claudio; Gardini, Marcello; Murray, Keith S., Inorganic Chemistry, 1987, vol. 26, # 21, p. 3539 - 3543

  摘要：

  DOI：

文献信息

• Reaction of μ-oxobis(phthalocyaninatoiron(III)) in pyridine/water. Evidence for a slow reacting oxophthalocyaninatoiron(IV) compound
  作者：Fabrizio Monacelli

  DOI：10.1016/s0020-1693(96)05174-2

  日期：1997.1

  The reaction of mu-oxobis(phthalocyaninatoiron(III)) in pyridine containing small amounts of water has been investigated. The reaction occurs in two consecutive steps. The first step is a disproportionation equilibrium (K = 1.0X10(-3) mol dm(-3) at 35 degrees C) yielding [(py)(2)Fe(II)(pc)] and the ferryl compound [(py)Fe(IV)(pc)O]. The spectrum of the latter in the 600-700 nm range shows the shape characteristic of phthalocyaninato derivatives with a high intensity Q band (epsilon = 7.5 X 10(4)) at 670 nm. During the succeeding step, that requires several hours to be completed, the Fe=O oxygen is transferred to peripheral sites of the macrocycle, very likely to form C-OH groups. This fact does not modify appreciably the electronic properties of the complex, if compared to those of [(py)(2)Fe(pc)], and can be revealed only by FAB experiments which show the presence of phthalocyaninato derivatives of mass 568 + 16 and 568 + 32 (568 being the mass of the molecular ion [Fe(pc)(+)]. The first step of this reaction represents a convenient method for preparing pyridine solutions of the ferrylic species, suitable for reactivity studies.