| 175697-17-3

• CAS: 175697-17-3
• 化学式: C₁₉H₁₆MoN₂O₄
• 分子量: 432.287
• InChiKey: NAAYFMPGWBZDNA-WHSVYILESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-acetylpyridine-1-phenylethylimine 、 molybdenum hexacarbonyl 以 正庚烷 为溶剂， 生成
  参考文献：
  名称：

  Syntheses, IR and multinuclear (1H, 13C, 31P, 95Mo) NMR investigation of molybdenum and tungsten carbonyl complexes containing bidentate nitrogen donor ligands

  摘要：

  Complexes of the type [M(CO)(4)(N-N')] [where M = Mo or W; N-N' = C5H4NC(R)=NCH(R')Ph (R = H or Me; R' = H or Me); C9H7 NCH=NCH(R')Ph (R' = H or Me)] and [Mo(CO)(3)(PR(3)){C5H4NCH=NCH(Me)Ph}] [where PR(3) = PEt(3), PPh(3), P(OEt)(3), 4-ethyl-2,6,7-trioxa-1-phosphabicycle[2.2.2] octane have been synthesized. They were characterized by elemental analyses, IR and NMR (H-1, C-13, P-31, Mo-95) spectroscopy. The stereochemistry of these complexes has been discussed on the basis of NMR data. Separate Mo-95 resonances have been observed for the mer form and diastereomers of the fac isomer of [Mo(CO)(3)(PR(3)){C5H4NCH=NCH(Me)Ph}] complexes.

  DOI：

  10.1016/0277-5387(95)00372-x