| 1094812-08-4

• CAS: 1094812-08-4
• 化学式: C₁₀₁H₁₃₂B₂F₄N₄O₄Si
• 分子量: 1591.88
• InChiKey: IMUOGZKQNTZCAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 甲醇 、 sodium hydroxide 作用下， 以 二氯甲烷 为溶剂， 反应 0.5h， 以95%的产率得到
  参考文献：
  名称：

  Phenylethynyl-BODIPY Oligomers: Bright Dyes and Fluorescent Building Blocks

  摘要：

  Boradiazaindacene dyes were converted Into phenylethynyl-BODIPY oligomers via a cycle of reactions, notably including Sonogashira couplings. As expected, as the number, n, of repeating units Increases, peak absorption and emission wavelengths are shifted to the red end of the visible spectrum, albeit with smaller increments as n Increases, Decyl groups help to keep the solubility remarkably high, and in addition to being very bright red-emitting fluorophores, their rigid rod-like structures could allow their use as functional building blocks.

  DOI：

  10.1021/ol802446e
• 作为产物：
  描述：

  、 4-(trimethylsilylethynyl)phenylacetylene 在 二异丙胺 、 bis-triphenylphosphine-palladium(II) chloride 、 copper(l) iodide 作用下， 以 四氢呋喃 为溶剂， 反应 12.25h， 以70%的产率得到
  参考文献：
  名称：

  Phenylethynyl-BODIPY Oligomers: Bright Dyes and Fluorescent Building Blocks

  摘要：

  Boradiazaindacene dyes were converted Into phenylethynyl-BODIPY oligomers via a cycle of reactions, notably including Sonogashira couplings. As expected, as the number, n, of repeating units Increases, peak absorption and emission wavelengths are shifted to the red end of the visible spectrum, albeit with smaller increments as n Increases, Decyl groups help to keep the solubility remarkably high, and in addition to being very bright red-emitting fluorophores, their rigid rod-like structures could allow their use as functional building blocks.

  DOI：

  10.1021/ol802446e