ytterbium tetraphenylphorphyrin chloride dimethoxyethane complex | 421548-42-7

• 英文名称: ytterbium tetraphenylphorphyrin chloride dimethoxyethane complex
• 英文别名: YbCl(5,10,15,20-tetraphenylporphyrinate)(1,2-dimethoxyethane)
• CAS: 421548-42-7
• 化学式: C₄₈H₃₈ClN₄O₂Yb
• 分子量: 911.348
• InChiKey: PLVXAWWSZXNATR-NBICUONBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ytterbium tetraphenylphorphyrin chloride dimethoxyethane complex 、 potassium acetylacetonate 以 乙二醇二甲醚 为溶剂， 以91%的产率得到ytterbium tetraphenylphorphyrin acetylacetonate complex
  参考文献：
  名称：

  Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes

  摘要：

  The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

  DOI：

  10.1021/ic015612e
• 作为产物：
  描述：

  ytterbium trichloride tris(tetrahydrofuran) 、 dilithiotetraphenylporphyrin bisdimethoxyethane 以 甲苯 为溶剂， 以75%的产率得到ytterbium tetraphenylphorphyrin chloride dimethoxyethane complex
  参考文献：
  名称：

  Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes

  摘要：

  The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

  DOI：

  10.1021/ic015612e

文献信息

• Facile Preparation and Photophysics of Near-Infrared Luminescent Lanthanide(III) Monoporphyrinate Complexes
  作者：Timothy J. Foley、Benjamin S. Harrison、Alison S. Knefely、Khalil A. Abboud、John R. Reynolds、Kirk S. Schanze、James M. Boncella

  DOI：10.1021/ic034217g

  日期：2003.8.1

  monoporphyrinate, trivalent lanthanide complexes with the monoanionic ligands hydridotris(1-pyrazolyl)borate (Tp) and (cyclopentadienyl)tris(diethylphosphinito)cobaltate (L(OEt)) having the general formulas M(TPP)(L) (M = Yb, Tm, Er, Ho, Nd, Pr; TPP = 5,10,15,20-tetraphenylporphyrinate; L = Tp, L(OEt)) are described. The photophysical properties of these complexes are also presented including their absorption

  一系列单卟啉，三价镧系元素与单阴离子配体氢化三（1-吡唑基）硼酸酯（Tp）和（环戊二烯基）三（二乙基膦基）钴（L（OEt）描述了具有通式M（TPP）（L）（M = Yb，Tm，Er，Ho，Nd，Pr; TPP = 5,10,15,20-四苯基卟啉酸酯; L = Tp，L（OEt）） 。还介绍了这些配合物的光物理性质，包括它们的吸收，发射和瞬态吸收性质。