2,12-bis[trans-Pt(PEt3)2Br]DTDA | 869641-36-1

• 英文名称: 2,12-bis[trans-Pt(PEt3)2Br]DTDA
• 英文别名: 2,12-bis[trans-Pt(PEt3)2Br]-7-(3,5-di-tert-butyl-phenyl)-5,6,8,9-tetrahydrodibenzo[c,h]acridine
• CAS: 869641-36-1
• 化学式: C₅₉H₉₅Br₂NP₄Pt₂
• 分子量: 1492.27
• InChiKey: DHAUCSQGGUYVDO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,12-bis[trans-Pt(PEt3)2Br]DTDA 以 二氯甲烷 、 水 、 丙酮 为溶剂， 生成 cyclo-bis[(2,12-bis(trans-Pt(PEt3)2)-7-(3,5-di-tert-butylphenyl)-5,6,8,9-tetrahydrodibenzo[c,h]acridine)(isonicotinic acid)2](NO3)4
  参考文献：
  名称：

  Self-Assembly of Rectangles and Prisms via a Molecular “Clip”

  摘要：

  Aromatic molecular "clips" bearing two symmetrically bound platinum moieties have been prepared. The molecular "clip" 4 readily self-assembled with linear linkers such as 4,4'-bipyridyl, 1,4-bis[2-(4-isocyano-3,5-diisopropylphenyl)ethynyl]benzene, and nicotinic acid to form molecular rectangles. The overall dimensions of the rectangle 7 were 7.3 angstrom x 15.3 angstrom. The molecular "clip" also self-assembled with tritopic pyridyl and isocyanide ligands to form trigonal prismatic frameworks. The characterization of the supramolecules by multinuclear NMR, electrospray mass spectrometry, and X-ray crystal structures is also reported.

  DOI：

  10.1021/ic0508369
• 作为产物：
  描述：

  2,12-dibromo-7-(3,5-di-tert-butyl-phenyl)-5,6,8,9-tetrahydrodibenzo[c,h]acridine 、 铂(三乙基膦)4 以 甲苯 为溶剂， 以89%的产率得到2,12-bis[trans-Pt(PEt3)2Br]DTDA
  参考文献：
  名称：

  Self-Assembly of Rectangles and Prisms via a Molecular “Clip”

  摘要：

  Aromatic molecular "clips" bearing two symmetrically bound platinum moieties have been prepared. The molecular "clip" 4 readily self-assembled with linear linkers such as 4,4'-bipyridyl, 1,4-bis[2-(4-isocyano-3,5-diisopropylphenyl)ethynyl]benzene, and nicotinic acid to form molecular rectangles. The overall dimensions of the rectangle 7 were 7.3 angstrom x 15.3 angstrom. The molecular "clip" also self-assembled with tritopic pyridyl and isocyanide ligands to form trigonal prismatic frameworks. The characterization of the supramolecules by multinuclear NMR, electrospray mass spectrometry, and X-ray crystal structures is also reported.

  DOI：

  10.1021/ic0508369