bis[1,3-bis(trimethylsilyl)cyclopentadienyl]yttrium chloride | 420087-26-9

• 英文名称: bis[1,3-bis(trimethylsilyl)cyclopentadienyl]yttrium chloride
• 英文别名: 1,1',3,3'-tetrakis(trimethylsilyl)yttrocene chloride
• CAS: 420087-26-9
• 化学式: C₂₂H₄₂ClSi₄Y
• 分子量: 543.276
• InChiKey: GHRPAUJKEUJMPM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 potassium (tris(tert-butyl)silyl)phosphanide 、 bis[1,3-bis(trimethylsilyl)cyclopentadienyl]yttrium chloride 以 四氢呋喃 为溶剂， 以65%的产率得到(tetrahydrofuran-O)-1,1',3,3'-tetrakis(trimethylsilyl)yttrocene-tri(tert-butyl)silylphosphanide
  参考文献：
  名称：

  Synthese und Strukturen von Yttrium-tris[bis(trimethylsilyl)phosphanid] und 1, 1', 3, 3'-Tetrakis(trimethylsilyl)yttrocen-tri(tert-butyl)silylphosphanid

  摘要：

  The metalation of HP(SiMe3)(2) with Y[CH(SiMe3)(2)](3) gives the homoleptic {Y[P(SiMe3)(2)](3)}(2) (1) which crystallizes from toluene in the monoclinic space group P2(1)/c. The yttrium. atoms are in a distorted tetrahedral environment with Y-P bond lengths of 267.7 and 284.8 pm to the terminal and bridging substituents, respectively. The metathesis reaction of [1,3-(Me3Si)(2)C5H3](2)YCl with KPSitBu(3) yields (tetrahydrofaran-O)-1,1',3,3'-tetrakis(trimethylsilyl)yttrocene-tri(tert-butyl)silylphosphanide (2). The molecular structure of 2 in solution was deduced by NMR spectroscopy and X-ray crystallography. The coupling constants (1)J(Y,P) and (1)J(P,H) show values of 144.0 Hz and 201.0 Hz, respectively.

  DOI：

  10.1002/1521-3749(200202)628:2<330::aid-zaac330>3.0.co;2-u