Cu2(3-methoxysalicylaldehyde O-(2-hydroxyethyl)oxime(2-))2 | 1007559-24-1

• 英文名称: Cu2(3-methoxysalicylaldehyde O-(2-hydroxyethyl)oxime(2-))2
• CAS: 1007559-24-1
• 化学式: C₂₀H₂₂Cu₂N₂O₈
• 分子量: 545.495
• InChiKey: MUCRRQZRHRTBMP-RQGQYRQLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-methoxy-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol 、 copper(II) acetate monohydrate 以 乙醇 为溶剂， 生成 Cu2(3-methoxysalicylaldehyde O-(2-hydroxyethyl)oxime(2-))2
  参考文献：
  名称：

  Study on Synthesis and Crystal Structure of an Unexpected Dialkoxo-Bridged Dinuclear Cu(II) Complex

  摘要：

  An unprecedented dinuclear copper(II) complex, [Cu-2(L-2)(2)] (H2L2 = 3-Methoxysalicylaldehyde O-(2-hydroxyethyl)oxime), has been synthesized via the complexation of copper(II) acetate monohydrate with unsymmetrical Salen-type ligand H2L1 (H2L1 = 3-Methoxy-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol). The crystal structure of the copper(II) complex has been determined by single-crystal X-ray diffraction method. The catalysis of copper(II) ions results in the unexpected cleavage of one of the N-O bonds in the ligand H2L1, giving a novel dialkoxo-bridged dinuclear copper(II) complex possessing a Cu-O-Cu-O four-membered ring core instead of the usually desired Salen-type bisoxime Cu-N2O2 mononuclear complex.

  DOI：

  10.1080/15533174.2011.613889

文献信息

• Synthesis and Crystal Structure of Dinuclear Copper(II) Complex with Salamo-Type Ligand
  作者：Wen-You Li、Xiang-Li、Meng-Meng Zhao、Gang Li、Xiu-Yan Dong

  DOI：10.14233/ajchem.2014.15866

  日期：——

  An unexpected dinuclear Cu(II) complex, [Cu2(L2)2] (H2L2 = 3-methoxysalicylaldehyde-O-(2-hydroxyethyl)oxime) has been synthesized through the complexation of Cu(OAc)2·H2O with an asymmetrical Salamo-type compound 6-ethyloxy-6-methoxy-2,2-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol (H2L1). The catalysis of Cu(II) ions results in the unexpected cleavage of one of the N-O bonds in the ligand H2L1, giving a novel dialkoxo-bridged dinuclear Cu(II) complex possessing a Cu-O-Cu-O four-membered ring core instead of the usually desired Salamo-type Cu-N2O2 mononuclear complex. In the crystal structure, two intermolecular hydrogen bonds, C2-H2B···O3 and C2-H2B···O4 linked the neighboring molecules into an infinite chain parallel to the a axis.

  通过Cu(OAc)2·H2O与不对称Salamo型化合物6-乙氧基-6-甲氧基-2,2-[乙二基二氧双(腈基甲基)]二苯酚（H2L1）的络合，意外地合成了二核Cu(II)络合物[Cu2(L2)2]（H2L2=3-甲氧基水杨醛-O-(2-羟基乙基)肟）。Cu(II)离子的催化作用导致配体H2L1中的一个N-O键意外断裂，形成了一种新型二烷氧基桥联二核Cu(II)络合物，其中心为Cu-O-Cu-O四元环，而不是通常所需的Salamo型Cu-N2O2单核络合物。在晶体结构中，两个分子间氢键（C2-H2B···O3和C2-H2B···O4）将相邻分子连接成平行于a轴的无限链。