[η5-C5H4CHN(CH3(CH)C10H7)]Fe[η5-C5H4P(t-Bu)2]Pd(I)(C6F5) | 1323187-56-9

• 英文名称: [η5-C5H4CHN(CH3(CH)C10H7)]Fe[η5-C5H4P(t-Bu)2]Pd(I)(C6F5)
• 英文别名: [N-1-(naphthylethyl)[1'-(di-tert-butylphosphino)-1-ferrocenyl]methylimine]Pd(I)(pentafluorophenyl)
• CAS: 1323187-56-9
• 化学式: C₃₇H₃₈F₅FeINPPd
• 分子量: 911.853
• InChiKey: ZQFFFHUMIWOLHK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [η5-C5H4CHN(CH3(CH)C10H7)]Fe[η5-C5H4P(t-Bu)2]Pd(I)(C6F5) 以 氘代四氢呋喃 为溶剂， 生成 [η5-C5H4CHN(CH3(CH)C10H7)]Fe[η5-C5H4P(t-Bu)2]Pd(dba)
  参考文献：
  名称：

  Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings

  摘要：

  A mixture of Pd-2(dba)(3)/{eta-C5H4CH=N[CH(CH3)(Nap)]}Fe[eta-C5H4P(Bu-t)(2)] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 x 10(-6) -1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd-2(dba)(3), the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.04.031
• 作为产物：
  描述：

  tris(dibenzylideneacetone)dipalladium (0) 、 2,3,4,5,6-五氟碘苯 、 N-1-(naphthylethyl)[1'-(di-tert-butylphosphino)-1-ferrocenyl]methylimine 以 氘代四氢呋喃 为溶剂， 生成 [η5-C5H4CHN(CH3(CH)C10H7)]Fe[η5-C5H4P(t-Bu)2]Pd(I)(C6F5)
  参考文献：
  名称：

  Ferrocenyl iminophosphine ligands in Pd-catalysed Suzuki couplings

  摘要：

  A mixture of Pd-2(dba)(3)/{eta-C5H4CH=N[CH(CH3)(Nap)]}Fe[eta-C5H4P(Bu-t)(2)] efficiently catalyzes the Suzuki reactions of a variety of bulky aryl halides and aryl- and alkyl-boronic acids, affording the desired cross-coupling biaryl products in quantitative isolated yields under mild conditions and at low (1 x 10(-6) -1 mol%) Pd loadings. Spectroscopic (NMR & ESI) analysis of the mixture of Pd-2(dba)(3), the hybrid [P,N] ligands, and aryl halides revealed different structural forms of oxidative addition products that are dependent on the substituent on the imino nitrogen. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.04.031