(1-pyrenyl)CH2PPh3Cl | 101363-24-0

• 英文名称: (1-pyrenyl)CH2PPh3Cl
• 英文别名: Triphenyl(pyren-1-ylmethyl)phosphanium;chloride
• CAS: 101363-24-0
• 化学式: C₃₅H₂₆P*Cl
• 分子量: 513.018
• InChiKey: ZNIXXNGDAUPORB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.08
• 重原子数：
  37
• 可旋转键数：
  5
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-ferrocenyl-2-propenal 、 (1-pyrenyl)CH2PPh3Cl 在 KOC(CH₃)3 、 I₂ 作用下， 以 四氢呋喃 为溶剂， 生成 (E,E)-(1-pyrenyl)butadienylferrocene
  参考文献：
  名称：

  乙烯基和乙炔基二茂铁多芳族二元化合物的合成，结构和氧化还原化学

  摘要：

  一系列二茂铁基-芳烃二联体，Fc-C⋮C-Ar，反式-Fc-CH CH-Ar和Fc-CH CH-CH合成了CH-Ar（Ar =苯基，1-萘基，2-萘基，9-菲基，9-蒽基，1-吡啶基，3-per基）。讨论了它们的结构和光谱电化学性质。已经通过X射线衍射确定了几种分子的结构，并将观察到的结构与总的自由能最小化的计算结构进行了比较。在固态下，所有乙炔基二元都有一个与二茂铁基环戊二烯基环正交的芳环，而计算预测其共面取向。所计算和观察到的结构对于乙烯基二元化合物是一致的，对于蒽基和pyr基二元化合物分别是正交的环和共面的环。在大多数情况下，固态结构通过多环烃环之间的偏移π堆积相互作用来稳定。中性二元组电子光谱中的两个谱带归因于各个芳基和二茂铁基端基。在[Fc]处氧化+ / 0对，二茂铁基跃迁被低能量的LMCT谱带所取代，而近红外光谱中的新弱谱带被赋予Fc + ←芳基跃迁；这些分配得到共振拉曼光谱的支持，并且Fc

  DOI：

  10.1021/om0492653

文献信息

• SILICON-CONTAINING PARTICLES, METHOD FOR MANUFACTURING THEREOF, OIL COMPOSITION, CERAMIC MATERIAL, AND METHOD FOR MANUFACTURING THEREOF
  申请人：Dow Corning Toray Co., Ltd.

  公开号：EP2271702A2

  公开（公告）日：2011-01-12
• Silicon-Containing Particles, Method For Manufacturing Thereof, Oil Composition, Ceramic Material, And Method For Manufacturing Thereof
  申请人：Harimoto Yukinari

  公开号：US20110045963A1

  公开（公告）日：2011-02-24

  This invention relates to a method for manufacturing silicon-containing particles characterized by preparing a uniform phase comprising a curable composition that includes a silicon-containing compound having in one molecule one or more reactive functional groups per 50 silicon atoms and an oil that does not participate in curing of the composition, then curing the composition, and causing phase separation from the oil for obtaining the silicon-containing particles; and to silicon-containing particles obtained by the above method. The method provides silicon-containing particles of an extremely small diameter in a simple process without the use of surfactants. And the silicon-containing particles possess excellent dispersibility in oil and a high degree of ceramification by baking.
• US8450231B2
  申请人：——

  公开号：US8450231B2

  公开（公告）日：2013-05-28
• [EN] SILICON-CONTAINING PARTICLES, METHOD FOR MANUFACTURING THEREOF, OIL COMPOSITION, CERAMIC MATERIAL, AND METHOD FOR MANUFACTURING THEREOF<br/>[FR] PARTICULES CONTENANT DU SILICIUM, LEUR PROCÉDÉ DE FABRICATION, COMPOSITION D'HUILE, MATÉRIAU CÉRAMIQUE ET SON PROCÉDÉ DE FABRICATION
  申请人：DOW CORNING TORAY CO LTD

  公开号：WO2009133765A2

  公开（公告）日：2009-11-05

  This invention relates to a method for manufacturing silicon-containing particles characterized by preparing a uniform phase comprising a curable composition that includes a silicon-containing compound having in one molecule one or more reactive functional groups per 50 silicon atoms and an oil that does not participate in curing of the composition, then curing the composition, and causing phase separation from the oil for obtaining the silicon-containing particles; and to silicon-containing particles obtained by the above method. The method provides silicon-containing particles of an extremely small diameter in a simple process without the use of surfactants. And the silicon-containing particles possess excellent dispersibility in oil and a high degree of ceramification by baking.