oxyphosphonitride | 113110-84-2

• 英文名称: oxyphosphonitride
• CAS: 113110-84-2
• 化学式: NOP
• 分子量: 60.9799
• InChiKey: XISXEABRPCPPBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.4
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  diphosphoryl azide 以 solid matrix 为溶剂， 生成 oxyphosphonitride
  参考文献：
  名称：

  Elusive O═P≡N, a Rare Example of Phosphorus σ²λ⁵-Coordination

  摘要：

  Two linear isomers, OPN and ONP, were formed in an Ar matrix at 16 K by ArF laser (lambda = 193 nm) photolysis of phosphoryl triazide, OP(N-3)(3), and comprehensively characterized by their mid- and far-IR spectra as well as N-14/15 isotopic data. Two intermediates, (N-3)(2)P(O)N and N3P(O)N-4, have been isolated in an Ar matrix and spectroscopically characterized. Photolysis of these intermediates using near-LTV/vis light (lambda > 320 rim) was shown to yield exclusively ONP, which under ArF laser irradiation selectively photo-isomerized to OPN. The photochemical and molecular properties of OPN and ONP are discussed on the basis of experimental and ab initio calculated results.

  DOI：

  10.1021/ja2091867