suspension cell culture of Mentha piperita L

• 英文名称: suspension cell culture of Mentha piperita L

反应信息

• 作为试剂：
  描述：

  (-)-isopiperitenone 在 palladium on activated charcoal 、 suspension cell culture of Mentha piperita L 氢气 作用下， 以 正己烷 为溶剂， 27.0 ℃ 、101.33 kPa 条件下， 反应 60.0h， 生成 (4S)-4-hydroxymenthone
  参考文献：
  名称：

  Modified Monoterpenes from Biotransformation of (−)-Isopiperitenone by Suspension Cell Culture of Mentha piperita

  摘要：

  The biotransformation of (-)-(4R)-isopiperitenone (1) by suspension cell culture of Mentha piperita yielded three new hydroxylated derivatives, 4-6, and two new epoxidized derivatives, 7 and 8. (-)-7-Hydroxyisopiperitenone (2) and its glucoside were previously isolated from the culture. The structures of 4-8 were elucidated using spectral methods, and their absolute stereochemistry was established by NMR experiments and correlation with compounds of known configuration.

  DOI：

  10.1021/np970388k