[(C5Me4H)2Lu][(μ-Ph)2BPh2] | 872871-69-7

• 英文名称: [(C5Me4H)2Lu][(μ-Ph)2BPh2]
• CAS: 872871-69-7
• 化学式: C₄₂H₄₆BLu
• 分子量: 736.605
• InChiKey: LDLQFFSSCMXJNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(C5Me4H)2Lu][(μ-Ph)2BPh2] 、 potassium tetramethylcyclopentadienide 以 苯 为溶剂， 以90%的产率得到lutetium(3+);1,2,4,5-tetramethylcyclopenta-1,3-diene
  参考文献：
  名称：

  The Elusive (C₅Me₄H)₃Lu:  Its Synthesis and LnZ₃/K/N₂ Reactivity

  摘要：

  The previously inaccessible smallest member of the (C5Me4H)(3)Ln series, (C5Me4H)(3)Lu, has been synthesized from [(C5Me4H)(2)Lu] [(mu-Ph)(2)BPh2] and KC5Me4H and reduced with potassium under dinitrogen to form [(C5Me4H)(2)(THF)Lu](2)(mu-eta(2):eta(2)-N-2).

  DOI：

  10.1021/om050709k
• 作为产物：
  描述：

  、 triethylammonium tetraphenylborate 以 苯 为溶剂， 以94%的产率得到[(C5Me4H)2Lu][(μ-Ph)2BPh2]
  参考文献：
  名称：

  The Elusive (C₅Me₄H)₃Lu:  Its Synthesis and LnZ₃/K/N₂ Reactivity

  摘要：

  The previously inaccessible smallest member of the (C5Me4H)(3)Ln series, (C5Me4H)(3)Lu, has been synthesized from [(C5Me4H)(2)Lu] [(mu-Ph)(2)BPh2] and KC5Me4H and reduced with potassium under dinitrogen to form [(C5Me4H)(2)(THF)Lu](2)(mu-eta(2):eta(2)-N-2).

  DOI：

  10.1021/om050709k