| 217815-52-6

• CAS: 217815-52-6
• 化学式: C₂₀H₃₆ClO₄PRu
• 分子量: 508.0
• InChiKey: OIBZSOQZKGSCCX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Selective two-phase-hydrogenation of sorbic acid with novel water soluble ruthenium complexes

  摘要：

  Neutral and cationic water soluble Cp*-ruthenium-complexes of the type [Cp*Ru(CO)Cl(PR3)] and [Cp*Ru(CO)(PR3)]CF3SO3 (R = CH2OH, (CH2)(3)OH, Ph-m-SO3Na) have been synthesized for the first time and have been used as catalysts in two-phase-hydrogenations. The neutral complexes have been fully characterized. But the cationic complexes which have not been isolated are effective catalysts for the selective hydrogenation of sorbic acid in water/n-heptane leading to the formation of cis-3-hexenoic acid and trans-3-hexenoic acid. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00874-2
• 作为产物：
  描述：

  (η(5)-C5Me5)Ru(CO)2Cl 、 三(3-羟基丙基)膦 以 not given 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Selective two-phase-hydrogenation of sorbic acid with novel water soluble ruthenium complexes

  摘要：

  Neutral and cationic water soluble Cp*-ruthenium-complexes of the type [Cp*Ru(CO)Cl(PR3)] and [Cp*Ru(CO)(PR3)]CF3SO3 (R = CH2OH, (CH2)(3)OH, Ph-m-SO3Na) have been synthesized for the first time and have been used as catalysts in two-phase-hydrogenations. The neutral complexes have been fully characterized. But the cationic complexes which have not been isolated are effective catalysts for the selective hydrogenation of sorbic acid in water/n-heptane leading to the formation of cis-3-hexenoic acid and trans-3-hexenoic acid. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00874-2