4-(4-Propanoylphenyl)sulfanylbenzoic acid | 1308733-23-4

• 英文名称: 4-(4-Propanoylphenyl)sulfanylbenzoic acid
• CAS: 1308733-23-4
• 化学式: C₁₆H₁₄O₃S
• 分子量: 286.351
• InChiKey: PASVCGRURASIRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  79.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-(4-Propanoylphenyl)sulfanylbenzoic acid 在 盐酸 、 亚硝酸异丁酯 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 3.5h， 生成 4-[4-(2-hydroxyiminopropanoyl)phenyl]sulfanylbenzoic acid
  参考文献：
  名称：

  Oxime ester compound and photopolymerization initiator containing the same

  摘要：

  公开号：

  EP2327689B1
• 作为产物：
  描述：

  4-苯基硫烷基苯甲酸 、 丙酰氯 在 aluminum (III) chloride 作用下， 以 1,1-二氯乙烷 为溶剂， 生成 4-(4-Propanoylphenyl)sulfanylbenzoic acid
  参考文献：
  名称：

  Oxime ester compound and photopolymerization initiator containing the same

  摘要：

  公开号：

  EP2327689B1

文献信息

• CURABLE RESIN COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2586827A1

  公开（公告）日：2013-05-01

  A curing resin composition that cures in two stages: photo cure and thermal cure, hardly contaminates a liquid or liquid crystals when in contact with, and provides high adhesive strength, particularly a curing composition that photocures sufficiently even when shadowed by TFT wires, a black matrix, etc. in photocuring; and a sealant, a sealant for ODF (one-drop-fill), and an LCD containing the curing resin composition. The curing resin composition contains (A) an oxime ester radical initiator represented by general formula (I), where symbols are as defined in the description, (B) a radical curing resin, (C) a latent epoxy curing agent, and (D) an epoxy resin.

  一种固化树脂组合物，其固化分为两个阶段：光固化和热固化，在与液体或液晶接触时几乎不会污染液体或液晶，并提供高粘合强度，特别是一种固化组合物，即使在光固化过程中被TFT导线、黑色矩阵等遮挡也能充分光固化；以及一种密封剂、一种用于ODF（一滴填充）的密封剂和一种含有该固化树脂组合物的液晶显示器。固化树脂组合物包含 (A) 由通式 (I) 表示的肟酯自由基引发剂，其中符号如描述中所定义；(B) 自由基固化树脂；(C) 潜伏环氧固化剂；以及 (D) 环氧树脂。
• OXIME ESTER COMPOUND AND PHOTOPOLYMERIZATION INITIATOR CONTAINING THE SAME
  申请人：MURATA Kiyoshi

  公开号：US20110129778A1

  公开（公告）日：2011-06-02

  The invention provides a novel compound useful as a highly-sensitive photopolymerization initiator that has excellent stability, low sublimability, excellent developability, and high transmittance in the visible region and that efficiently absorbs, and is activated by, near-ultraviolet rays such as at 365 nm. Also provided are a photopolymerization initiator and a photosensitive composition using the above-described compound. Specifically, the invention provides an oxime ester compound represented by the following general formula (I), a photopolymerization initiator containing the same, and a photosensitive composition containing the photopolymerization initiator and a polymerizable compound having an ethylenically unsaturated bond: wherein, R 1 and R 2 each represent R 11 , COR 11 , CONR 12 R 13 , CN, etc.; R 11 , R 12 , and R 13 each represent a C 1-20 alkyl group, etc.; R 3 and R 4 each represent R 11 , OR 11 , COR 11 , CONR 12 R 13 , OCOR 11 , CN, a halogen atom, etc.; a and b each represent an integer of 0 to 4; X represents an oxygen atom, a sulfur atom, etc.; and R 5 represents OH, COOH, or a group represented by general formula (II).
• CURING RESIN COMPOSITION
  申请人：Shinano Hirokatsu

  公开号：US20120115972A1

  公开（公告）日：2012-05-10

  A curing resin composition that cures in two stages: photo cure and thermal cure, hardly contaminates a liquid or liquid crystals when in contact with, and provides high adhesive strength, particularly a curing composition that photocures sufficiently even when shadowed by TFT wires, a black matrix, etc. in photocuring; and a sealant, a sealant for ODF (one-drop-fill), and an LCD containing the curing resin composition. The curing resin composition contains (A) an oxime ester radical initiator represented by general formula (I), where symbols are as defined in the description, (B) a radical curing resin, (C) a latent epoxy curing agent, and (D) an epoxy resin.
• US8148045B2
  申请人：——

  公开号：US8148045B2

  公开（公告）日：2012-04-03
• US8735511B2
  申请人：——

  公开号：US8735511B2

  公开（公告）日：2014-05-27