(μ-SCH2)2N(CH2C6H5)[Fe2(CO)4(tris(N-pyrrolyl)phosphine)2] | 1021186-13-9

• 英文名称: (μ-SCH2)2N(CH2C6H5)[Fe2(CO)4(tris(N-pyrrolyl)phosphine)2]
• CAS: 1021186-13-9
• 化学式: C₃₇H₃₅Fe₂N₇O₄P₂S₂
• 分子量: 879.503
• InChiKey: UCKYTLFHAJVFSS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (μ-SCH2)2N(CH2C6H5)[Fe2(CO)4(tris(N-pyrrolyl)phosphine)2] 在 三(2,2'-联吡啶)钌II 作用下， 以 乙腈 为溶剂， 生成 (μ-SCH2)2N(CH2C6H5)[Fe2(CO)4(tris(N-pyrrolyl)phosphine)2](1-)
  参考文献：
  名称：

  Visible Light-Driven Electron Transfer and Hydrogen Generation Catalyzed by Bioinspired [2Fe2S] Complexes

  摘要：

  Complexes [{(mu-SCH2)(2)NCH2C6H5){Fe(CO)(2)L-1){Fe(CO)(2)L-2}] (L-1 = CO, L-2 = P(Pyr)(3), 2; L-1 = L-2 = P(Pyr)(3), 3) were prepared, which have the lowest reduction potentials for the mono- and double-CO-displaced diiron complexes reported so far. Hydrogen evolution, driven by visible light, was successfully observed for a three-component system, consisting of a ruthenium polypyridine complex, the biomimetic model complex 2 or 3, and ascorbic acid as both electron and proton donor in CH3CN/H2O. The electron transfer from photogenerated Ru(bPY)(3)(+) to 2 or 3 was detected by laser flash photolysis. Under optimal conditions, the total turnover number for hydrogen evolution was 4.3 based on 2 and 86 based on Ru(bPY)(3)(2+) in a three-hour photolysis.

  DOI：

  10.1021/ic702010w
• 作为产物：
  描述：

  tri-1-pyrrolylphosphine 、 {(μ-SCH2)2NCH2C6H5}Fe2(CO)5P(Pyr)3 以 甲苯 为溶剂， 以65%的产率得到(μ-SCH2)2N(CH2C6H5)[Fe2(CO)4(tris(N-pyrrolyl)phosphine)2]
  参考文献：
  名称：

  Visible Light-Driven Electron Transfer and Hydrogen Generation Catalyzed by Bioinspired [2Fe2S] Complexes

  摘要：

  Complexes [{(mu-SCH2)(2)NCH2C6H5){Fe(CO)(2)L-1){Fe(CO)(2)L-2}] (L-1 = CO, L-2 = P(Pyr)(3), 2; L-1 = L-2 = P(Pyr)(3), 3) were prepared, which have the lowest reduction potentials for the mono- and double-CO-displaced diiron complexes reported so far. Hydrogen evolution, driven by visible light, was successfully observed for a three-component system, consisting of a ruthenium polypyridine complex, the biomimetic model complex 2 or 3, and ascorbic acid as both electron and proton donor in CH3CN/H2O. The electron transfer from photogenerated Ru(bPY)(3)(+) to 2 or 3 was detected by laser flash photolysis. Under optimal conditions, the total turnover number for hydrogen evolution was 4.3 based on 2 and 86 based on Ru(bPY)(3)(2+) in a three-hour photolysis.

  DOI：

  10.1021/ic702010w