| 406911-92-0

• CAS: 406911-92-0
• 化学式: C₂₅H₂₇BrClNORu
• 分子量: 573.922
• InChiKey: UXRXNSDBDFEDRJ-RUQUECPNSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  A new heterogeneous hybrid ruthenium catalyst being an eco-friendly option for the production of polymers and organic intermediates

  摘要：

  我们成功合成并表征了一种新型的异质混合钌催化剂，该催化剂表现出优良的稳定性、可重复使用性和浸出特性。通过XRD、XRF、ICP/MS、BET、FT-Raman和固态NMR分析研究了宿主–客体相互作用。此外，我们在环闭合交叉反应（RCM）、环打开交叉聚合（ROMP）、卡拉什加成、原子转移自由基聚合（ATRP）和乙烯化反应中测试了该催化系统。测试结果表明，在ROMP、RCM、卡拉什加成和乙烯化反应中，该异质催化剂相比其均相类似物具有重要优势。

  DOI：

  10.1039/b202872g
• 作为产物：
  描述：

  thallium(I) 2-(((4-bromo-2,6-dimethylphenyl)imino)methyl)phenolate 、 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  A new class of ruthenium complexes containing Schiff base ligands as promising catalysts for atom transfer radical polymerization and ring opening metathesis polymerization

  摘要：

  A novel series of Schiff base ruthenium complexes that are active catalysts in the field of atom transfer radical polymerization (ATRP), have been prepared. Moreover, when activated with trimethylsilyldiazomethane (TMSD), these species exhibit good catalytic activity in the ring opening metathesis polymerization (ROMP) of norbornene and cyclooctene. The activity for both the ROMP and ATRP reaction is dependent on the steric bulk and electron donating ability of the Schiff base ligand. The control over polymerization in ATRP was verified for the two substrates that exhibit the highest activity, namely MMA and styrene. The results show that the optimal ATRP equilibrium leading to a controlled polymerization, can be established by adjusting the steric and electronic properties of the Schiff base ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(01)00451-4