[CuCl2(1,2-bis(o-aminophenoxy)ethane)2] | 612480-16-7

• 英文名称: [CuCl2(1,2-bis(o-aminophenoxy)ethane)2]
• CAS: 612480-16-7
• 化学式: C₂₈H₃₂Cl₂CuN₄O₄
• 分子量: 623.038
• InChiKey: AZRRFBOHSFTFRB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [CuCl2(1,2-bis(o-aminophenoxy)ethane)2] 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Thermal analysis study of some transition metal complexes by TG and DSC methods

  摘要：

  The thermodynamic and thermal properties of [Cu(L)(2).Cl-2], [Ni(L)(2)].Cl-2, [Co(L)(2).Cl-2]; L= 1,2-bis( o-aminophenoxy) ethane (BAFE), complexes have been investigated. The thermal decomposition of the complexes took place in two distinct steps in endothermic reaction up to 700 degreesC. The activation energy E, the entropy change DeltaS(#), enthalpy DeltaH change and Gibbs free energy change DeltaG(#) were calculated from the results of thermogravimetry analysis (TG) and heat capacity from the results of differential scanning calorimetry (DSC). It was found that the thermal stabilities and activation energies of the complexes follow the order Ni(II)> Cu(II)> Co(II) and E-Co< E-Ni< E-Cu, respectively.

  DOI：

  10.1023/b:jtan.0000017341.20105.22
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 2,2’-二氨基乙二醇二苯醚 以 乙醇 为溶剂， 生成 [CuCl2(1,2-bis(o-aminophenoxy)ethane)2]
  参考文献：
  名称：

  Thermal analysis study of some transition metal complexes by TG and DSC methods

  摘要：

  The thermodynamic and thermal properties of [Cu(L)(2).Cl-2], [Ni(L)(2)].Cl-2, [Co(L)(2).Cl-2]; L= 1,2-bis( o-aminophenoxy) ethane (BAFE), complexes have been investigated. The thermal decomposition of the complexes took place in two distinct steps in endothermic reaction up to 700 degreesC. The activation energy E, the entropy change DeltaS(#), enthalpy DeltaH change and Gibbs free energy change DeltaG(#) were calculated from the results of thermogravimetry analysis (TG) and heat capacity from the results of differential scanning calorimetry (DSC). It was found that the thermal stabilities and activation energies of the complexes follow the order Ni(II)> Cu(II)> Co(II) and E-Co< E-Ni< E-Cu, respectively.

  DOI：

  10.1023/b:jtan.0000017341.20105.22