(bis[pentakis(trimethylsilyl)ferrocenyl])diselane | 639818-30-7

• 英文名称: (bis[pentakis(trimethylsilyl)ferrocenyl])diselane
• CAS: 639818-30-7
• 化学式: C₅₀H₉₈Fe₂Se₂Si₁₀
• 分子量: 1249.8
• InChiKey: TYQFATLRTRZKPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 (bis[pentakis(trimethylsilyl)ferrocenyl])diselane 以 二氯甲烷 为溶剂， 生成 (bis[pentakis(trimethylsilyl)ferrocenyl])diselane*CH2Cl2
  参考文献：
  名称：

  Synthesis and structure of free and complexed cyclopentadienyl selanes

  摘要：

  Substitution of cyclopentadiene by one to three Me(3)Si or t-Bu groups allows the formation of mono- and biscyclopentadienylmono-, di-, and triselanes. [(Me(3)Si)(3)C(5)H(2)](2)Se(2) is the first biscyclopentadienyldiselane characterized by single crystal X-ray diffraction. Crystal structures are also presented to show that such compounds can function as ligands via selenium or the cyclopentadienyl moieties. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00041-0
• 作为产物：
  描述：

  lithium tris(trimethylsilyl)cyclopentadienylselenolat 、 iron(II) chloride 以 四氢呋喃 为溶剂， 以6.33%的产率得到(bis[pentakis(trimethylsilyl)ferrocenyl])diselane
  参考文献：
  名称：

  Synthesis and structure of free and complexed cyclopentadienyl selanes

  摘要：

  Substitution of cyclopentadiene by one to three Me(3)Si or t-Bu groups allows the formation of mono- and biscyclopentadienylmono-, di-, and triselanes. [(Me(3)Si)(3)C(5)H(2)](2)Se(2) is the first biscyclopentadienyldiselane characterized by single crystal X-ray diffraction. Crystal structures are also presented to show that such compounds can function as ligands via selenium or the cyclopentadienyl moieties. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00041-0