[RuCl(η(6)-p-cymene)(2-diphenylphosphinopicolinamide-P,O)] | 823838-16-0

• 英文名称: [RuCl(η(6)-p-cymene)(2-diphenylphosphinopicolinamide-P,O)]
• CAS: 823838-16-0
• 化学式: C₂₈H₂₈ClN₂OPRu
• 分子量: 576.04
• InChiKey: IRXWKMTXNRRLGS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 [RuCl(η(6)-p-cymene)(2-diphenylphosphinopicolinamide-P,O)] 以 氘代氯仿 为溶剂， 生成 [RuCl(η(6)-p-cymene)(2-diphenylphosphinopicolinamide-P,O)]*0.5CH2Cl2
  参考文献：
  名称：

  Synthesis and coordination of 2-diphenylphosphinopicolinamide

  摘要：

  The synthesis and coordination of 2-diphenylphosphinopicolinamide (dpppa 1) is reported. Coordination complexes with Pd, Pt, Ru, Rh, Ir and Au are described. The ligand behaves as a monodentate P donor in complexes such as [PtCl2(dpppa-P-2)], [PdCl(allyl)(dpppa-P)], [RuCl2(p-Cymene)(dpppa-P)], cis-[PtCl2(dpppa-P)(PR3)] and [AuCl(dpppa-P)]. Bidentate P, O coordination was accomplished by reaction of BuLi with [RuCl2(p-Cymene)(dpppa-P)], to give [RuCl(p-Cymene)(dpppa-P,O). P,N donor behaviour was achieved by reaction of a monodentate complex with a halide abstractor [AgBF4] generating [RuCl(p-Cymene)(dpppa-P,N)][ClO4] and [RhCl(eta(5)hCl(eta(5)-C5Me5)(dpppa-P,N)][BF4]. The X-ray structures of dpppa, dpppaO, dpppaS, four monodentate complexes and [RuCl(p-Cymene)(dpppa-P,O) are reported. All of the structures contain intramolecular N-(HN)-N-... hydrogen bonding. (C) 2004 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2004.10.004
• 作为产物：
  描述：

  [(η6-p-cymene)(3-NC5H4C(O)NHP(C6H5)2)ruthenium(II)Cl2] 在 BuLi 作用下， 以 四氢呋喃 为溶剂， 以52%的产率得到[RuCl(η(6)-p-cymene)(2-diphenylphosphinopicolinamide-P,O)]
  参考文献：
  名称：

  Synthesis and coordination of 2-diphenylphosphinopicolinamide

  摘要：

  The synthesis and coordination of 2-diphenylphosphinopicolinamide (dpppa 1) is reported. Coordination complexes with Pd, Pt, Ru, Rh, Ir and Au are described. The ligand behaves as a monodentate P donor in complexes such as [PtCl2(dpppa-P-2)], [PdCl(allyl)(dpppa-P)], [RuCl2(p-Cymene)(dpppa-P)], cis-[PtCl2(dpppa-P)(PR3)] and [AuCl(dpppa-P)]. Bidentate P, O coordination was accomplished by reaction of BuLi with [RuCl2(p-Cymene)(dpppa-P)], to give [RuCl(p-Cymene)(dpppa-P,O). P,N donor behaviour was achieved by reaction of a monodentate complex with a halide abstractor [AgBF4] generating [RuCl(p-Cymene)(dpppa-P,N)][ClO4] and [RhCl(eta(5)hCl(eta(5)-C5Me5)(dpppa-P,N)][BF4]. The X-ray structures of dpppa, dpppaO, dpppaS, four monodentate complexes and [RuCl(p-Cymene)(dpppa-P,O) are reported. All of the structures contain intramolecular N-(HN)-N-... hydrogen bonding. (C) 2004 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2004.10.004