| 210177-38-1

• CAS: 210177-38-1
• 化学式: C₁₂H₂₀N₂O₂Rh₂S₄
• 分子量: 558.378
• InChiKey: MBHHKSLTBVIUDE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  The reactivity of [Rh(S2CNEt2) (CO)2] towards HpzAn

  摘要：

  The reaction of [Rh(S2CNEt2)(CO)(2)] and Hpz(An) (3(5)-p-methoxyphenylpyrazole) in acetone at room temperature yields to a mixture of [Rh(mu-pz(An))(S2CNEt2)(CO)](2) (2) and [Rh(S2CNEt2)(3)] (3). The same results were obtained from the reaction of [RhCl(CO)(2)(H-pz(An))] with NaS2CNEt2. The first reaction in boiling solvents (acetone, dichloromethane) didn't yield to the binuclear complex (2) but an unexpected complex [Rh(S2CNEt2)(CO)](2) (1) was obtained. Complex (1) was proved to be the evolution result of the starting [Rh(S2CNEt2)(CO)(2)] in boiled solvents. The molecular structure of complex (3) has been determined. Crystals of (3) are monoclinic, space group C2/c, and is a different form than that previously reported for [Rh(S2CNEt2)(3)]. Subtle differences between the molecular structures are also found. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00385-9