(tris(2-O,3-(1-adamantyl),5-tert-butylbenzyl)amine)TiCl | 874892-51-0

• 英文名称: (tris(2-O,3-(1-adamantyl),5-tert-butylbenzyl)amine)TiCl
• CAS: 874892-51-0
• 化学式: C₆₃H₈₄ClNO₃Ti
• 分子量: 986.698
• InChiKey: IVBSGDPIUANILK-VDBGSJHZSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (tris(2-O,3-(1-adamantyl),5-tert-butylbenzyl)amine)TiCl 、 silver trifluoromethanesulfonate 以 四氢呋喃 为溶剂， 以82%的产率得到(tris(2-O,3-(1-adamantyl),5-tert-butylbenzyl)amine)TiOSO2CF3
  参考文献：
  名称：

  Titanium complexes supported by a sterically encumbering N-anchored tris-arylphenoxide ligand

  摘要：

  A family of neutral and cationic Ti(IV) complexes supported by the sterically demanding and trianionic ligand (O3N)(3-)(O3N3-(O3N3- = tris(2-0,3-Ad,5-tBubenzyl)amine, Ad = 1-adamantyl) have been prepared from the hydrolysis of TiCl4(THF)(2) with the free base (O3N)H-3 and excess NEt3, followed by anion exchange reactions. These (O3N)Ti+ cores are resistant to moisture and air, are mononuclear, and possess C-3 symmetry on the NMR timescale. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.06.028
• 作为产物：
  描述：

  tetrachlorobis(tetrahydrofuran)titanium(IV) 、 tris(2-OH,3-(1-adamantyl),5-tert-butylbenzyl)amine 在 triethyl amine 作用下， 以 甲苯 为溶剂， 以90%的产率得到(tris(2-O,3-(1-adamantyl),5-tert-butylbenzyl)amine)TiCl
  参考文献：
  名称：

  Titanium complexes supported by a sterically encumbering N-anchored tris-arylphenoxide ligand

  摘要：

  A family of neutral and cationic Ti(IV) complexes supported by the sterically demanding and trianionic ligand (O3N)(3-)(O3N3-(O3N3- = tris(2-0,3-Ad,5-tBubenzyl)amine, Ad = 1-adamantyl) have been prepared from the hydrolysis of TiCl4(THF)(2) with the free base (O3N)H-3 and excess NEt3, followed by anion exchange reactions. These (O3N)Ti+ cores are resistant to moisture and air, are mononuclear, and possess C-3 symmetry on the NMR timescale. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.06.028