| 299184-51-3

• CAS: 299184-51-3
• 化学式: C₂₂H₅₁ClN₂O₂P₂Ru
• 分子量: 574.13
• InChiKey: WYSWIOAKNGHQAA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  chloro(hydrido)ruthenium;tri(propan-2-yl)phosphane 、 1-(二甲氨基)-2-硝基乙烯 以 苯 为溶剂， 生成 、 chlororuthenium(1+);N,N-dimethyl-2-nitroethenamine;tri(propan-2-yl)phosphane
  参考文献：
  名称：

  Reactivity of [RuHCl(PⁱPr₃)₂]₂ with Functionalized Vinyl Substrates. The H₂ Ligand as a Sensitive Probe of Electronic Structure

  摘要：

  Reaction of [RuHClL2](2) (L = (PPr3)-Pr-i) with 2-vinylpyridine gives L2ClRu(eta(2)-CH=CHC5H4N) with liberation of H-2. Reaction of [RuHClL2](2) with a range of olefins D(H)C=CR(EWG) substituted by electron-donating (D) and -withdrawing (EWG) groups occurs by oxidative addition of a vinyl C-H bond to give the metallacycles L2ClHnRu(eta(2)-double dagger C(D)=CR(EWG)). The C-13 chemical shift of double dagger C and the fate of the "H-n" unit (decoordination, binding as H-2, or binding as two hydrides) are strongly correlated, depend on the donating and withdrawing power of D and EWG, and can be used to decide whether double dagger C binds to Ru as a carbene or as a vinyl. These results emphasize the reducing power of Ru(II) when pi-acid ligands such as CO are absent.

  DOI：

  10.1021/ic9905998