1,10-phenanthroline-5-yl-1,2-ferrocenylethanol | 869654-01-3

• 英文名称: 1,10-phenanthroline-5-yl-1,2-ferrocenylethanol
• CAS: 869654-01-3
• 化学式: C₂₄H₂₀FeN₂O
• 分子量: 408.283
• InChiKey: OFQKOAYSCCOPRP-ZEECNFPPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,10-phenanthroline-5-yl-1,2-ferrocenylethanol 在 4-甲基苯磺酸吡啶 作用下， 以 甲苯 为溶剂， 以82%的产率得到5-((E)-2-ferrocenylvinyl)-1,10-phenanthroline
  参考文献：
  名称：

  Intramolecular excited state quenching: 5-[(E)-2-ferrocenylvinyl]-1,10-phenanthroline, a new donor ligand

  摘要：

  The new 5-[(E)-2-ferrocenylvinyl]-1,10-phenanthroline ligand and its corresponding ruthenium complex were synthesized. In these compounds, the ferrocenyl moiety acts like an electron donor while the phenanthroline region acts as an acceptor. By irradiation with light of appropriate wavelength ferrocenyl to phenanthroline charge transfer absorption bands were observed. The ruthenium bis bipyridine complex formed with this new ligand shows no interaction between the Ru and Fe metal centers in the ground state. In the excited state, the absence of photoluminescence from the Ru center evidences a quenching process, probably of electron transfer nature. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2005.05.007
• 作为产物：
  描述：

  二茂铁甲醛 、 5-甲基-1,10-菲咯啉 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 以52%的产率得到1,10-phenanthroline-5-yl-1,2-ferrocenylethanol
  参考文献：
  名称：

  Intramolecular excited state quenching: 5-[(E)-2-ferrocenylvinyl]-1,10-phenanthroline, a new donor ligand

  摘要：

  The new 5-[(E)-2-ferrocenylvinyl]-1,10-phenanthroline ligand and its corresponding ruthenium complex were synthesized. In these compounds, the ferrocenyl moiety acts like an electron donor while the phenanthroline region acts as an acceptor. By irradiation with light of appropriate wavelength ferrocenyl to phenanthroline charge transfer absorption bands were observed. The ruthenium bis bipyridine complex formed with this new ligand shows no interaction between the Ru and Fe metal centers in the ground state. In the excited state, the absence of photoluminescence from the Ru center evidences a quenching process, probably of electron transfer nature. (c) 2005 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2005.05.007