[(Cp*)2Sc(OCMe2)2]BPh4 | 1308718-26-4

• 英文名称: [(Cp*)2Sc(OCMe2)2]BPh4
• 英文别名: [(Cp*)2Sc(acetone)2]BPh4
• CAS: 1308718-26-4
• 化学式: C₂₄H₂₀B*C₂₆H₄₂O₂Sc
• 分子量: 750.808
• InChiKey: QIRYMJQHGOTDKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  decamethylscandocene*BPh4 、 丙酮 以 further solvent(s) 为溶剂， 生成 [(Cp*)2Sc(OCMe2)2]BPh4
  参考文献：
  名称：

  Reactivity of cationic decamethylmetallocene complexes towards ketones

  摘要：

  Reaction of decamethylmetallocene cations [Cp-2*M](+) (M = Sc, Ti, V) with acetone and benzophenone resulted in the formation of the corresponding acetone adducts [Cp-2*M(OCMe2)(n)](+) (M = Sc, n = 2; M = Ti, n = 1; M = V, n = 1) and benzophenone adducts [Cp-2*M(OCPh)](+). The stoichiometry of these adducts is determined by both the electronic configuration of the metal center as well as steric pressure imparted by the large Cp*-ligands. In addition, the M-O-C angle is controlled by the number of free valence orbitals of the Cp-2*M unit. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.02.023