| 68480-87-5

• CAS: 68480-87-5
• 化学式: C₂₄H₁₈Cl₂CuN₂
• 分子量: 468.872
• InChiKey: NYQLQAAWPFYYKW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 5H-茚并[1,2-b]吡啶 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Interaction of copper(II) halides with 4-azafluorene derivatives in neutral and acid media. Crystal and molecular structure of 4-aza-9-oxofluorenium tetrabromocuprate hydrate (HL4)2CuB4 · H2O

  摘要：

  Complexes of copper(II) halides ( chlorides and bromides) with some 4-azafluorene derivatives have been synthesized and studied by X-ray crystallography and IR and UV spectroscopy. In neutral media, Cu(L)(2)X-2 (X = Cl, Br) complexes are formed in which the ligands are coordinated to the metal atoms though the lone pair of the endocyclic nitrogen atom and through the oxygen atoms of substituents. In acid media at pH 2, (HL2)(2)Cu-4 complexes are formed in which the 4-azafluorene molecules protonated at the endocyclic nitrogen atom act as an outer-sphere cation. The molecule and crystal structure of 4-aza-9-oxofluorenium tetrabromocuprate hydrate (HL4)(2)CuBr4 center dot H2O has been determined.

  DOI：

  10.1134/s0036023607050130