[PtBrMe2(2,2'-bipyridine)(CH2-c-C3H5)] | 1268168-61-1

• 英文名称: [PtBrMe2(2,2'-bipyridine)(CH2-c-C3H5)]
• 英文别名: [PtBrMe2(bipy)(CH2-c-C3H5)]
• CAS: 1268168-61-1
• 化学式: C₁₆H₂₁BrN₂Pt
• 分子量: 516.34
• InChiKey: DYMXGJHQKLUCND-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PtBrMe2(2,2'-bipyridine)(CH2-c-C3H5)] 、 silver trifluoroacetate 以 not given 为溶剂， 生成 [Pt(CF3CO2)Me2(bipy)(CH2-c-C3H5)]
  参考文献：
  名称：

  Reactivity and mechanism in the ring-opening of cyclopropylmethylplatinum(IV) complexes

  摘要：

  The oxidative addition of cyclopropylmethyl or cyclobutylmethyl bromide to [PtMe2(bipy)], 1. bipy=2,2'-bipyridine, gave the products of trans-oxidative addition [PtBrMe2(CH2-c-C3H5)(bipy)], 2. or [PtBrMe2(CH2-c-C4H7)(bipy)], 3. These compounds are thermally stable but the complex [Pt(O2CCF3)Me-2(CH2-c-C3H5)(biPY)] rearranges on heating to give the ring-opened complex [Pt(O2CCF3)Me-2(CH2CH2CH=CH2)(bipy)]. Factors affecting the reactivity towards ring-opening are discussed. (c) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.09.044
• 作为产物：
  描述：

  溴甲基环丁烷 、 dimethyl(2,2'-bipyridine)platinum(II) 、 溴甲基环丙烷 以 not given 为溶剂， 生成 [PtBrMe2(2,2'-bipyridine)(CH2-c-C3H5)] 、 [PtBrMe2(2,2'-bipyridine)(CH2-c-C4H7)]
  参考文献：
  名称：

  Reactivity and mechanism in the ring-opening of cyclopropylmethylplatinum(IV) complexes

  摘要：

  The oxidative addition of cyclopropylmethyl or cyclobutylmethyl bromide to [PtMe2(bipy)], 1. bipy=2,2'-bipyridine, gave the products of trans-oxidative addition [PtBrMe2(CH2-c-C3H5)(bipy)], 2. or [PtBrMe2(CH2-c-C4H7)(bipy)], 3. These compounds are thermally stable but the complex [Pt(O2CCF3)Me-2(CH2-c-C3H5)(biPY)] rearranges on heating to give the ring-opened complex [Pt(O2CCF3)Me-2(CH2CH2CH=CH2)(bipy)]. Factors affecting the reactivity towards ring-opening are discussed. (c) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.09.044