[(hydrotris(pyrazolyl)borate)RuCl(1,2-bis(diisopropylphosphino)ethane)] | 192201-49-3

• 英文名称: [(hydrotris(pyrazolyl)borate)RuCl(1,2-bis(diisopropylphosphino)ethane)]
• 英文别名: (hydrotris(pyrazolyl)borate)RuCl(1,2-bis(diisopropylphosphino)ethane)
• CAS: 192201-49-3
• 化学式: C₂₃H₄₂BClN₆P₂Ru
• 分子量: 611.908
• InChiKey: RPFPEXVQSFUDOP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(hydrotris(pyrazolyl)borate)RuCl(1,2-bis(diisopropylphosphino)ethane)] 在 KOBu(t) 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 生成 (hydrotris(pyrazolyl)borate)Ru(-C*CH)(1,2-bis(diisopropylphosphino)ethane)
  参考文献：
  名称：

  Reactivity of [TpRuCl(dippe)] toward 1-Alkynes. X-ray Crystal Structures of [TpRuC(OMe)CH₂COOMe(dippe)][BPh₄] and [TpRu(C⋮CC(Ph)CH₂)(dippe)] (dippe = 1,2-Bis(diisopropylphosphino)ethane; Tp = Hydrotris(pyrazolyl)borate)

  摘要：

  DOI：

  10.1021/om970543q
• 作为产物：
  描述：

  [(hydrotris(pyrazolyl)borate)RuH(1,2-bis(diisopropylphosphino)ethane)] 在 chlorinated solvents 作用下， 以 not given 为溶剂， 生成 [(hydrotris(pyrazolyl)borate)RuCl(1,2-bis(diisopropylphosphino)ethane)]
  参考文献：
  名称：

  Tenorio, Manuel Jimenez; Tenorio, Miguel Angel Jimenez; Puerta, M. Carmen, Inorganica Chimica Acta, 1997, vol. 259, p. 77 - 84

  摘要：

  DOI：

文献信息

• Synthesis and properties of hydrotris(pyrazolyl)borate (Tp) ruthenium complexes with benzophenone imine: X-ray crystal structure of [TpRu(HN=CPh2)(PEt3)2][BPh4]
  作者：Miguel Angel Jiménez-Tenorio、Manuel Jiménez-Tenorio、M.Carmen Puerta、Pedro Valerga

  DOI：10.1016/s0020-1693(00)00002-5

  日期：2000.4

  The complexes [TpRuCl(dippe)] (dippe = 1,2-bis(diisopropylphosphino)ethane) and [TpRuCl(PEt3)(2)] react with HN=CPh2 and NaBPh4 in MeOH affording the cationic mononuclear imine derivatives [TpRu(HN=CPh2)(dippe)][BPh4] and [TpRu(HN=CPh2)(PEt3)(2)][BPh4], respectively. The X-ray crystal structure of the latter has been determined. The reaction of [TpRuCl(PMePr2)((MeCN)-C-i)] with HN=CPh2 led to the neutral imine derivative [TpRuCl((PMePr2)-Pr-i)(HN=CPh2)], which adds a second imine ligand upon chloride dissociation affording the cationic bis(imine) complex [TpRu((PMePr2)-Pr-i)(HN=CPh2)(2)](+). The cationic complexes [TpRu(HN=CPh2)(dippe)][BPh4] and [TpRu(HN=CPh2)(PE3)(2)][BPh4] react with KOBut in tetrahydrofuran yielding the neutral metalated species [TpRu(sigma-eta(1)-C6H4C(Ph)=NH)(dippe)] and the phenyl complex [TpRu(sigma-eta(1)-C6H5)(PEt3)(2)], respectively. All compounds were characterized by IR, NMR and microanalysis. (C) 2000 Elsevier Science S.A. All rights reserved.