| 89119-68-6

• CAS: 89119-68-6
• 化学式: C₁₇H₁₂Cl₂HgMoN₂O₃
• 分子量: 659.73
• InChiKey: OSQHXFLWHMYIEW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 acetone 作用下， 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of carbonyl complexes containing MoHg bonds; reaction of tin(II) halides with [Mo(CO)3(NN)(HgX)(X)] (NN = bpy, phen, dmp); crystal structure of [Mo(CO)3(dmp)(HgCl)(Cl)]

  摘要：

  Reaction of HgCl2 with [Mo(CO),(dmp)] (dmp = 2,9-dimethyl-1,10-phenanthroline) gives the heterobimetallic compound [MO(CO)3(dmp)(HgCl)(Cl)] (I), which gives rise to a new compound [Mo(CO)3(dmp)(HgCl)(Cl)] . 1/2(CH3)2CO (II) in acetone solution at low temperature. The crystal structure of I has been solved and the compound shown to be a capped trigonal prism containing Mo-Hg-Cl and Mo-Cl bonds. The reactions of the above and related heteronuclear complexes [MO(CO)3(NN)(HgX)(X)] [X = Cl, Br; NN = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)] with tin (II) halides were studied. No insertion of the latter into the metal-metal or metal-halogen bonds were observed, with only bimetallic tricarbonyl complexes containing Mo-Hg bonds being isolated.

  DOI：

  10.1016/s0277-5387(00)80095-9
• 作为产物：
  描述：

  (2,9-dimethyl-1,10-phenanthroline)molybdenum tetracarbonyl 、 mercury dichloride 以 丙酮 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Reactivity of carbonyl complexes containing MoHg bonds; reaction of tin(II) halides with [Mo(CO)3(NN)(HgX)(X)] (NN = bpy, phen, dmp); crystal structure of [Mo(CO)3(dmp)(HgCl)(Cl)]

  摘要：

  Reaction of HgCl2 with [Mo(CO),(dmp)] (dmp = 2,9-dimethyl-1,10-phenanthroline) gives the heterobimetallic compound [MO(CO)3(dmp)(HgCl)(Cl)] (I), which gives rise to a new compound [Mo(CO)3(dmp)(HgCl)(Cl)] . 1/2(CH3)2CO (II) in acetone solution at low temperature. The crystal structure of I has been solved and the compound shown to be a capped trigonal prism containing Mo-Hg-Cl and Mo-Cl bonds. The reactions of the above and related heteronuclear complexes [MO(CO)3(NN)(HgX)(X)] [X = Cl, Br; NN = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen)] with tin (II) halides were studied. No insertion of the latter into the metal-metal or metal-halogen bonds were observed, with only bimetallic tricarbonyl complexes containing Mo-Hg bonds being isolated.

  DOI：

  10.1016/s0277-5387(00)80095-9

文献信息

• Reactivity of the complexes Mo(CO)3(η2-NN)(η1-(dppm) (NN = bpy, phen, dmp) with HgX2 (X = Cl, Br, I, CN, SCN). Formation of trimetallic MoHgMo and bimetallic MoHg complexes
  作者：M. Cano、J.A. Campo

  DOI：10.1016/s0277-5387(00)81336-4

  日期：1991.1

  employed. The formation of the trinuclear complexes [Mo(CO)3(η2-NN)(X)]2Hg is favoured over the expected bimetallic derivatives, in which two metals are bridged by the dppm ligand. Bimetallic compounds are obtained when bulky ligands are present, such as dmp bonded to a molybdenum atom or I bonded to mercury, and only in the latter case is a MoHg complex bridged by dppm obtained.

  摘要配合物[Mo（CO）3（η2-NN）（η1-dppm）]的反应[NN = 2,2'-联吡啶（bpy），1,10-菲咯啉（phen），2,9-二甲基-1,10-菲咯啉（dmp）; dppm =双（二苯基膦基）甲烷与HgX2（X = Cl，Br，I，CN，SCN）生成三种类型的化合物[Mo（CO）3（η2-NN）（X）] 2Hg（NN = bpy， phen; X = Cl，Br，CN，SCN。NN = dmp; X = CN），[Mo（CO）3（η2-NN）（μ-dppm）HgI] HgI3，（NN = bpy，phen; X = I）和[Mo（CO）3（η2-dmp）（HgX）（X）]（X = Cl，Br，I，SCN），具体取决于所使用的NN-配体和汞衍生物。三核配合物[Mo（CO）3（η2-NN）（X）] 2Hg的形成优于预期的双金属衍生物，其中两种金属被dppm配体桥接。当存在庞大
• Reactivity of carbonyl complexes with MoHg bond. Interaction of tricarbonyl complexes of molybdenum(0) with thiourea and mercury chloride
  作者：A. Lopez、M. Panizo、M. Cano

  DOI：10.1016/0022-328x(86)80227-3

  日期：1986.9

  Addition of thiourea to (chloromercuri)molybdenum carbonyl complexes of the type NNMo(CO)3(HgCl)(Cl) (NN = 2,2′-bipyridine (bipy); 1,10-phenanthroline (phen); 2,9-dimethyl-1,10-phenanthroline (dmp)), give novel compounds in which the MoHg bond is retained.

  将硫脲添加到NNMo（CO）3（HgCl）（Cl）型（NN = 2,2'-联吡啶（bipy）; 1,10-菲咯啉（phen）; 2,9-二甲基-1,10-菲咯啉（dmp））产生保留MoHg键的新型化合物。