| 97286-53-8

• CAS: 97286-53-8
• 化学式: C₃₇H₂₆MoOS₂
• 分子量: 646.685
• InChiKey: WUTYYYLZFCVSJY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 2,2'-联吡啶 作用下， 以 乙二醇二甲醚 为溶剂， 以<50的产率得到{Mo(dpt)2(CO)2(bipy)}
  参考文献：
  名称：

  P. T. Bishop; Blower, P. J.; Dilworth, J. R., Polyhedron, 1986, vol. 5, p. 363 - 368

  摘要：

  DOI：
• 作为产物：
  描述：

  dibromotetracarbonylmolybdenum(II) 、 sodium-2,6-diphenylthiophenolate 以 乙二醇二甲醚 为溶剂， 以73.3%的产率得到
  参考文献：
  名称：

  A monomeric molybdenum thiolato-complex with a chelated η⁶-arene ligand. The preparation and structure of [Mo{(η⁶-Ph)PhC₆H₃S-2,6}(SC₆H₃Ph₂-2,6)(CO)]

  摘要：

  2,6-二苯基苯硫酚钠与[MoBr2(CO)4]反应生成螯合δ-6-烯复合物[Mo{(δ-6-Ph)PhC6H3S-2,6}(SC6H3Ph2-2,6)(CO)](1)，收率很高。

  DOI：

  10.1039/c39850000257

文献信息

• Co-ordination chemistry of 2,6-diphenylthiophenol. The syntheses and X-ray crystal structures of some molybdenum and rhodium complexes with σ- or η⁶-phenyl–metal interactions
  作者：Peter T. Bishop、Jonathan R. Dilworth、Terrence Nicholson、Jon Zubieta

  DOI：10.1039/dt9910000385

  日期：——

  Reaction of [MoCl2(CO)4] with the 2,6-diphenylthiophenolate anion (dpt) gives the complex [Mo(eta-6-dpt)(dpt)(CO)], with one thiol phenyl substituent eta-6-bonded to the molybdenum. Crystal data: space group P2(1)/c with a = 13.939(3), b = 10.548(3), c = 20.863(5) angstrom, beta = 106.88(1)-degrees and Z = 4. The eta-6-arene ligand is labile and is reversibly replaced by CO. Replacement of this ligand also occurs with 2,2'-bipyridyl(dipy),1,10-phenanthroline (phen), and 1,2-bis(diphenylphosphino)ethane (dppe) to give the dicarbonyl complexes [Mo(dpt)2(CO)2L] (L = bipy or phen) or the monocarbonyl complex [Mo(dpt)2(CO)(dppe)]. The X-ray crystal structure of the bipy derivative and the mechanism of its formation is discussed. Crystal data: space group P2(1)/c with a = 10.567(3), b = 22.843(5), c = 18.341(3) angstrom, beta = 105.2(2)-degrees and Z = 4. Reaction of RhCl3 with dpt gave the dinuclear species [Rh2mu-SC6H3(C6H4)-2-Ph-6}2(dpt)2(NCMe)2]. An X-ray crystal structure reveals that each bridging thiolate ligand is also sigma-bonded to rhodium [Rh-C 2.016(8) angstrom] via one of the phenyl carbons of the thiolate substituents. Crystal data: space group P2(1)/n, a = 11.991(2), b = 20.426(4), c = 15.910(4) angstrom, beta = 90.42(1) and Z = 2.