[Cp(*)RhCl]2(μ-C2S4) | 230625-85-1

• 英文名称: [Cp(*)RhCl]2(μ-C2S4)
• CAS: 230625-85-1
• 化学式: C₂₂H₃₀Cl₂Rh₂S₄
• 分子量: 699.461
• InChiKey: LOSODKOAISOQOV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cp(*)RhCl]2(μ-C2S4) 在 LiBHEt₃ 作用下， 以 四氢呋喃 为溶剂， 以55%的产率得到(Me5C5)2Rh2(ethylenetetrathiolate)
  参考文献：
  名称：

  Aufbau Approach to Multimetallic Ensembles Based on Tetrathiooxalate:  [Cp*₄Rh₄(C₂S₄)₂]²⁺, [Cp*₃Rh₂Ru(C₂S₄)]⁺, and [Cp*₆Rh₆(C₂S₄)₂]⁴⁺

  摘要：

  Experiments aimed at the characterization of new coordination modes for tetrathiooxalate (TTO) are described. Cyclic voltammetric (CV) measurements on Cp*Rh-2(2)(C2S4) (1) revealed an irreversible oxidation as part of an ECE process that results in the chemically reversible; dimerization of 1(+). Treatment of 1 with CpFe[C5H4C(O)Me]BF4 followed by anion exchange gave [Cp*Rh-4(4)(C2S4)(2)](BPh4)(2), the dicatiori of which consists of a dimer of is linked through two pairs of Rh-S bonds. A second new bonding mode for TTO was generated by treatment of 1 with [Cp*Ru(MeCN)(3)]PF6 to give [Cp*3Rh2Ru(C2S4)](+) (3) wherein Cp*Ru+ is eta (5)-bonded to one RhS2C2 ring. A third new bonding mode for TTO is illustrated by [Cp*Rh-6(6)(C2S4)(2)](4+), formed by the reaction of Cp*Rh(MeCN)(3)(2+) and 1. The structure can be viewed as a dimer of 3, except that there are no M-M bonds: the Cp*Rh2+ fragments are bonded via an eta (4)-interaction to RhS2C2 rings. Furthermore, the [Cp*Rh-3(3)(C2S4)](2+) subunits, which are otherwise isoelectronic with 3, dimerize, such that all eight sulfur atoms are triply bridging.

  DOI：

  10.1021/om000521v
• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 Ditetraethylammoniumtetrathiooxalat 以 甲醇 为溶剂， 以76%的产率得到[Cp(*)RhCl]2(μ-C2S4)
  参考文献：
  名称：

  Holloway, Geoffrey A.; Rauchfuss, Thomas B., Inorganic Chemistry, 1999, vol. 38, # 13, p. 3018 - 3019

  摘要：

  DOI：

文献信息

• Holloway, Geoffrey A.; Rauchfuss, Thomas B., Inorganic Chemistry, <hi>1999</hi>, vol. 38, # 13, p. 3018 - 3019
  作者：Holloway, Geoffrey A.、Rauchfuss, Thomas B.

  DOI：——

  日期：——