{(C5H5)Ru[C5H4-C(Me)NNH2]} | 1592939-19-9

• 英文名称: {(C5H5)Ru[C5H4-C(Me)NNH2]}
• 英文别名: {(C₅H₅)Ru[C₅H₄-C(Me)NNH₂]}
• CAS: 1592939-19-9
• 化学式: C₁₂H₁₄N₂Ru
• 分子量: 287.327
• InChiKey: XTWZKGQQTGCEAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(CMe₂CH₂C(Me)OSn)₄S₆] 、 {(C5H5)Ru[C5H4-C(Me)NNH2]} 以 二氯甲烷 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Synthesis, Crystal Structure, and Photoluminescence Studies of a Ruthenocenyl-Decorated Sn/S Cluster

  摘要：

  Recently, we reported on ferrocenyl-decorated Sn/S clusters; herein, we present the extension of our investigations by attachment of ruthenocenyl units to an according cluster skeleton. The latter was realized upon improvement of the synthesis of acetylruthenocene, its conversion to a hydrazone derivative, and the subsequent reaction with a keto-functionalized Sn/S precursor complex. The report comprises the crystal structures of acetylruthenocene and the ruthenocenyl-terminated Sn/S cluster [((RSn)-Sn-Rc)(4)Sn2S10] (R-Rc = CMe2CH2C(Me)=N-N=C(Me)Rc), as well as the discussion of the electrochemical properties of the latter and its behavior during time-resolved photoluminescence investigations.

  DOI：

  10.1021/ic500367y
• 作为产物：
  描述：

  acetylruthenocene 在 肼 作用下， 以 四氢呋喃 、 乙醇 、 二氯甲烷 为溶剂， 反应 8.0h， 生成 {(C5H5)Ru[C5H4-C(Me)NNH2]}
  参考文献：
  名称：

  Synthesis, Crystal Structure, and Photoluminescence Studies of a Ruthenocenyl-Decorated Sn/S Cluster

  摘要：

  Recently, we reported on ferrocenyl-decorated Sn/S clusters; herein, we present the extension of our investigations by attachment of ruthenocenyl units to an according cluster skeleton. The latter was realized upon improvement of the synthesis of acetylruthenocene, its conversion to a hydrazone derivative, and the subsequent reaction with a keto-functionalized Sn/S precursor complex. The report comprises the crystal structures of acetylruthenocene and the ruthenocenyl-terminated Sn/S cluster [((RSn)-Sn-Rc)(4)Sn2S10] (R-Rc = CMe2CH2C(Me)=N-N=C(Me)Rc), as well as the discussion of the electrochemical properties of the latter and its behavior during time-resolved photoluminescence investigations.

  DOI：

  10.1021/ic500367y