{2-[2-(phenylselanyl)ethyliminomethyl]phenolato}nickel(II) chloride | 1428258-68-7

• 英文名称: {2-[2-(phenylselanyl)ethyliminomethyl]phenolato}nickel(II) chloride
• CAS: 1428258-68-7
• 化学式: C₁₅H₁₄ClNNiOSe
• 分子量: 397.385
• InChiKey: CEXLLBWAQOKFBO-LPMXOWGUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水杨醛 在 potassium hydroxide 作用下， 以 乙醇 为溶剂， 反应 5.0h， 生成 {2-[2-(phenylselanyl)ethyliminomethyl]phenolato}nickel(II) chloride
  参考文献：
  名称：

  New sulfanyl- and selanyl-substituted Schiff bases derived from 2-chalcogenoalkylamines and aromatic aldehydes. Synthesis and complex formation reactions

  摘要：

  A number of beta-phenyl(or benzyl)selanyl- and beta-phenylsulfanyl-substituted imines possessing an additional donor nitrogen, oxygen, or sulfur atom were synthesized by reaction of 2-phenylsulfanylethanamine, 2-phenylsulfanylcyclohexanamine, 2-phenylselanylcyclohexanamine, and 2-benzylselanylaniline with salicylaldehyde, 2-pyridinecarbaldehyde, or 2-tert-butylsulfanylbenzaldehyde. The resulting Schiff bases were tested as ligands in the complex formation with nickel(II) and copper(II), and mononuclear (L-H)MCl or LMCl2 coordination compounds were isolated (L = sulfur- or selenium-containing imine). The redox properties of the selenium-containing ligands and complexes were studied by cyclic voltammetry. The complexes were found to undergo reduction of the metal ion in two one-electron steps. The reduction is reversible for copper complexes and irreversible for nickel complexes. DOI: 10.1134/S1070363213020138

  DOI：

  10.1134/s1070363213020138