4,6-bis{2-[(4-allyloxyphenylimino)methyl]-4-methyl-6-(2-phenylpropan-2-yl)phenoxy}titanium(IV) dichloride | 1267397-35-2

• 英文名称: 4,6-bis{2-[(4-allyloxyphenylimino)methyl]-4-methyl-6-(2-phenylpropan-2-yl)phenoxy}titanium(IV) dichloride
• CAS: 1267397-35-2
• 化学式: C₅₂H₅₂Cl₂N₂O₄Ti
• 分子量: 887.782
• InChiKey: GQZOSLFALYQNMH-GTJODXJGSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-(烯丙氧基)苯胺 在 盐酸 、 三乙胺 作用下， 以 甲醇 、 二氯甲烷 、 水 、 甲苯 为溶剂， 反应 24.0h， 生成 4,6-bis{2-[(4-allyloxyphenylimino)methyl]-4-methyl-6-(2-phenylpropan-2-yl)phenoxy}titanium(IV) dichloride
  参考文献：
  名称：

  Design of postmetallocene catalytic systems of arylimine type for olefin polymerization: XIV. Synthesis of (N-Allyloxyaryl)salicylaldimine ligands and their complexes with titanium(IV) dichloride

  摘要：

  By reaction of salicylaldehydes with bulky substituents in the positions 3 and 5 with o-, m-, and p-allyloxyaniline hydrochlorides in the presence of triethylamine a series of the corresponding (N-aryl)-salicylaldimines was obtained, which with TiCl2(OPr-i)(2) afforded complexes of titanium(IV) dichloride L2TiCl2.

  DOI：

  10.1134/s1070428012080076

文献信息

• Specific features of ethylene polymerization on self-immobilizing catalytic systems based on titanium bis(phenoxy imine) complexes
  作者：N. I. Ivancheva、V. K. Badaev、E. V. Sviridova、D. A. Nikolaev、I. V. Oleinik、S. S. Ivanchev

  DOI：10.1134/s1070427211010204

  日期：2011.1

  The kinetics of ethylene polymerization on six methylalumoxane-activated self-immobilizing bis(phenoxy imine) complexes of titanium chloride with allyloxy groups in the m- and p-positions of the N-phenyl ring and with various substituents in the salicylaldehyde fragment was studied. The activity of the complexes in the temperature range 20-60A degrees C and ethylene pressure of 0.4 MPa was evaluated.