[Pd(((η5-C5H3)CH=N(C6H4-2-SMe))Fe(η5-C5H5))Cl] | 657414-34-1

• 英文名称: [Pd(((η5-C5H3)CH=N(C6H4-2-SMe))Fe(η5-C5H5))Cl]
• 英文别名: [Pd([(ηC5H3)-CH=N-(C6H4-2-SMe)]Fe(η5-C5H5))Cl]
• CAS: 657414-34-1
• 化学式: C₁₈H₁₆ClFeNPdS
• 分子量: 476.118
• InChiKey: QFKANKVBCVJLFS-YOCKTNRLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd(((η5-C5H3)CH=N(C6H4-2-SMe))Fe(η5-C5H5))Cl] 、 三苯基膦 以 苯 为溶剂， 以87%的产率得到[Pd([(η5-C5H3)-CH=N-(C6H4-2-SMe)]Fe(η5-C5H5))(triphenylphosphine)Cl]
  参考文献：
  名称：

  Factors affecting the lability of the σ(M–X) bond in cycloplatinated and cyclopalladated complexes containing [C(sp2, ferrocene),N,X]− or [C(sp2, phenyl),N,X]− (X=S, N) terdentate ligands

  摘要：

  The reactions of the cyclometallated complexes [M {[(n(5)-C5H3)-CH=N-(C6H4-2-SMe)]Fe(n(5)-C5H5)}Cl] [with M = Pt (5a) or Pd (5b)] with PPh3 under different experimental conditions are reported.These studies have allowed the isolation of [M{[(eta(5)- C5H3)-CH=N-C6H4-2-SMe]Fe(eta(5)-C5H5)}(PPh3)]X [M = Pt and X- = Cl- (6a) or BF4- (7a) or M = Pd and X- = Cl- (6b) or BF4- (7b)] and the neutral complex [Pd{[eta(5)-C5H3)-CH=N-(C6H4-2-SMe)]Fe(eta(5)-C5H5)}Cl(PPh3)] (8b). In 6-7a,b the ferrocenyl Schiff base behaves as a [C(sp(2), ferrocene),N,S](-) group while in 8b it acts as a [C(SP2, ferrocene),N](-) ligand. The X-ray crystal structure of 7b confirms the mode of binding of the ferrocenyl ligand.The comparison of the results obtained and those reported for [M{(C6H4)-CH=N-(CH2-CH2-2-SEt)}Cl] and [M{(C6H4)-CH=N-(C6H4-2-SMe)Cl] {with a [C(SP2, phenyl),N,S](-) terdentate ligand} or [M{eta(5)-C5H3)-CH=N-(CH2)(3)-NMe2]Fe(eta(5)-C5H5)}Cl] {in which the ligand acts as a [C(sp(2), ferrocene),N,N'](-) group} have allowed the elucidation of the relative importance of the factors affecting the lability of the M-X (X = S or N') and M-Cl bonds in cyclometallated compounds with [C,N,S](-) and [C(sp(2), ferrocene),N,X](-) ligands. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.07.007

文献信息

• Study of the reactivity of palladacycles containing [C(sp2, ferrocene),N,S]− or [C(sp3),N,S]− terdentate ligands with symmetric alkynes
  作者：Concepción López、Sonia Pérez、Xavier Solans、Mercè Font-Bardía

  DOI：10.1016/j.jorganchem.2004.09.017

  日期：2005.1

  arises from 2c by cleavage of the Pd–S bond and the incorporation of a PPh3 in the coordination sphere of the palladium. A parallel study focused on the reactions of [Pd[2-CH2–4,6-Me2–C6H2]–CHN–(C6H4–2-SMe)}Cl] (1d) (with a [Csp3,N,S]− terdentate group) with the three alkynes reveals that the σPd–C(sp2, ferrocene)] bond of 1c is more reactive than the σ[Pd–C(sp3)] bond of 1d.

  的反应性的研究的环钯络合物[钯[（η 5 -C 5 H ^ 3）-CHN-（C 6 H ^ 4 -2-SME）]的Fe（η 5 -C 5 H ^ 5）} CL]（报告了带有炔烃R 1 –CC–R 1（其中R 1  = CO 2 Me，Ph或Et）的1c）。化合物1c在回流CH 2 Cl中与等摩尔量的MEO 2 C–CC–CO 2 Me反应2，得到[钯[（MEO 2 C-CC-CO 2 Me）的（η 5 -C5 ħ 3）-CHN-（C 6 H ^ 4 -2-SME）]的Fe（η 5 -C 5 H ^ 5）} CL]（2C），其起自炔的monoinsertion到σ [的Pd-C （sp 2，二茂铁）]键。但是，当使用Ph–CC–Ph或Et–CC–Et进行反应时，没有证据表明这些炔烃插入σ [Pd–C（sp 2，二茂铁）]。与这些结果相反，当用Tl [BF 4 ]处理1c后，除去形成的TlCl，随后添加MEO