| 223244-24-4

• CAS: 223244-24-4
• 化学式: C₁₄H₃₄Cl₂NO₂ScSi₂
• 分子量: 420.462
• InChiKey: AZOHBWIDADQTOF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  [ScCl2{N(SiMe3)2}(THF)2] als Vorläufer für die Synthese von Scandiumnitrid

  摘要：

  [ScCl2{N(SiMe3)(2)}(THF)(2)] (1) has been prepared by the reaction of [ScCl3(THF)(3)] with the trisamide SC[N(SiMe3)(2)](3) in tetrahydrofurane solution forming colourless moisture sensitive crystals, which were characterized by a crystal structure determination. Space group P (1) over bar, Z = 2, lattice dimensions at -50 degrees C: a = 841.4(1), b = 924.2(1), c = 1550.0(1) pm, alpha = 90.046(7)degrees, beta = 95.671(9)degrees, gamma = 106.066(6)degrees, R-1 = 0.0329. In the molecular structure of 1 the scandium atom has a distorted trigonal-bipyramidal coordination with the THF molecules in apical positions. At 400 degrees C 1 is converted into scandium nitride, ScN, by stepwise leaving of THF and ClSiMe3.

  DOI：

  10.1002/(sici)1521-3749(199903)625:3<375::aid-zaac375>3.0.co;2-t
• 作为产物：
  描述：

  sodium hexamethyldisilazane 、 氯化钪 以 四氢呋喃 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  [ScCl2{N(SiMe3)2}(THF)2] als Vorläufer für die Synthese von Scandiumnitrid

  摘要：

  [ScCl2{N(SiMe3)(2)}(THF)(2)] (1) has been prepared by the reaction of [ScCl3(THF)(3)] with the trisamide SC[N(SiMe3)(2)](3) in tetrahydrofurane solution forming colourless moisture sensitive crystals, which were characterized by a crystal structure determination. Space group P (1) over bar, Z = 2, lattice dimensions at -50 degrees C: a = 841.4(1), b = 924.2(1), c = 1550.0(1) pm, alpha = 90.046(7)degrees, beta = 95.671(9)degrees, gamma = 106.066(6)degrees, R-1 = 0.0329. In the molecular structure of 1 the scandium atom has a distorted trigonal-bipyramidal coordination with the THF molecules in apical positions. At 400 degrees C 1 is converted into scandium nitride, ScN, by stepwise leaving of THF and ClSiMe3.

  DOI：

  10.1002/(sici)1521-3749(199903)625:3<375::aid-zaac375>3.0.co;2-t