cis,trans-[PtCl2(OH)2(N(4)-isobutyryl-1,2,4-triaminobutane)] * H2O | 198144-36-4

• 英文名称: cis,trans-[PtCl2(OH)2(N(4)-isobutyryl-1,2,4-triaminobutane)] * H2O
• CAS: 198144-36-4
• 化学式: C₈H₂₁Cl₂N₃O₃Pt*H₂O
• 分子量: 491.274
• InChiKey: WPGDSZLVWXDWSS-USEIYGKDSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cis,trans-[PtCl2(OH)2(N(4)-isobutyryl-1,2,4-triaminobutane)] * H2O 、 乙酸酐 以 乙酸酐 为溶剂， 生成
  参考文献：
  名称：

  Platinum(IV) complexes of vicinal-1,2-diamines and bis(vicinal-1,2-diamines) with an acylamino function. Evidence for a platinum hydroperoxide intermediate upon oxidation

  摘要：

  By oxidation of mononuclear and dinuclear platinum(II) complexes having as ligands N4-acylated 1,2,4-triaminobutane units with H2O2 an intermediate was observed, probably a platinum bound hydroperoxide which is stabilized by hydrogen bonding to the acyl function in the side chain. Such an intermediate could not be isolated in the oxidation of [Cl2PtLLPtCl2] to the platinum(IV) complexes [(Ho)(2)Cl2PtLLPtCl2(OH)(2)] (LL = 1,2,9,10-tetraaminodecane or 1,2,11,12-tetraaminododecane). The synthesis of several mononuclear and dinuclear diamine tetrachloro platinum(IV) complexes is reported. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05594-1
• 作为产物：
  描述：

  N(4)-(COCH(CH3)2)-1,2,4-butanetriaminedichloro platinum(II) 、 双氧水 以 水 为溶剂， 生成 cis,trans-[PtCl2(OH)2(N(4)-isobutyryl-1,2,4-triaminobutane)] * H2O
  参考文献：
  名称：

  Platinum(IV) complexes of vicinal-1,2-diamines and bis(vicinal-1,2-diamines) with an acylamino function. Evidence for a platinum hydroperoxide intermediate upon oxidation

  摘要：

  By oxidation of mononuclear and dinuclear platinum(II) complexes having as ligands N4-acylated 1,2,4-triaminobutane units with H2O2 an intermediate was observed, probably a platinum bound hydroperoxide which is stabilized by hydrogen bonding to the acyl function in the side chain. Such an intermediate could not be isolated in the oxidation of [Cl2PtLLPtCl2] to the platinum(IV) complexes [(Ho)(2)Cl2PtLLPtCl2(OH)(2)] (LL = 1,2,9,10-tetraaminodecane or 1,2,11,12-tetraaminododecane). The synthesis of several mononuclear and dinuclear diamine tetrachloro platinum(IV) complexes is reported. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05594-1