[Pd((4-phenyl-3-ido)pyrimidin)(μ-Cl)]2 | 108115-95-3

• 英文名称: [Pd((4-phenyl-3-ido)pyrimidin)(μ-Cl)]2
• 英文别名: [Pd(ppm)(μ-Cl)]2
• CAS: 108115-95-3
• 化学式: C₂₀H₁₄Cl₂N₄Pd₂
• 分子量: 594.104
• InChiKey: YJSUKELMZYEGDG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pd((4-phenyl-3-ido)pyrimidin)(μ-Cl)]2 、 sodium perchlorate 、 乙二胺 以 甲醇 为溶剂， 以60%的产率得到(2-phenylpyrimidinato-C(2'),N(1))ethylenediaminepalladium(II) perchlorate
  参考文献：
  名称：

  Cyclopalladated ethylenediamine complexes on the basis of 4-phenylpyrimidine and 4,6-diphenylpyrimidine

  摘要：

  Mono- and binuclear cyclopalladated complexes [Pd(ppm)En]C104, [Pd(Hdphpm)En]C104, and [(PdEn),)([t-dphpm)1Cl04 (ppm- is the deprotonated form ol'4-phenylpyridine, Hdphpm- and dphpm 2- are the mono- and bisdeprotonated forms of 4,6-diphenylpyrimidine, En is 1,2-diaminoethane) were prepared and characterized by means of 'H NMR and electronic absorption and emission spectroscopy, and cyclic voltammetry. It was shown that cyclopalladation leads to a bathochromic shift of intraligand absorption and phosphorescence bands, appearance of new absorption band associated with metal-to-ligand charge transfer, and an anodic potential shift of the ligand-centered electroreduction Hppm - H,dphpm < [Pd(ppm)En]+z [Pd(Hdphpm)Enl' < [(PdEn)2(p-dphpn-i)]21.

  DOI：

  10.1134/s1070363208060236
• 作为产物：
  描述：

  4-苯基嘧啶 、 lithium tetrachloropalladate 以 not given 为溶剂， 生成 [Pd((4-phenyl-3-ido)pyrimidin)(μ-Cl)]2
  参考文献：
  名称：

  Cyclopalladated ethylenediamine complexes on the basis of 4-phenylpyrimidine and 4,6-diphenylpyrimidine

  摘要：

  Mono- and binuclear cyclopalladated complexes [Pd(ppm)En]C104, [Pd(Hdphpm)En]C104, and [(PdEn),)([t-dphpm)1Cl04 (ppm- is the deprotonated form ol'4-phenylpyridine, Hdphpm- and dphpm 2- are the mono- and bisdeprotonated forms of 4,6-diphenylpyrimidine, En is 1,2-diaminoethane) were prepared and characterized by means of 'H NMR and electronic absorption and emission spectroscopy, and cyclic voltammetry. It was shown that cyclopalladation leads to a bathochromic shift of intraligand absorption and phosphorescence bands, appearance of new absorption band associated with metal-to-ligand charge transfer, and an anodic potential shift of the ligand-centered electroreduction Hppm - H,dphpm < [Pd(ppm)En]+z [Pd(Hdphpm)Enl' < [(PdEn)2(p-dphpn-i)]21.

  DOI：

  10.1134/s1070363208060236