| 207115-11-5

• CAS: 207115-11-5
• 化学式: C₅₀H₄₀Cl₄Mn₂N₈
• 分子量: 1004.61
• InChiKey: LOEODPVGXZIMOV-JYTBHRTJSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶-2-甲醛 、 4,4'-二氨基二苯甲烷 、 manganese(II) chloride tetrahydrate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Study of olefin epoxidation using binuclear Mn(II) complexes as catalyst in presence and absence of UV light

  摘要：

  Mn(II) binuclear complexes of Schiff base ligands have been synthesised by the reaction of MnCl2.2H(2)O in ethanolic solution with the Schiff base obtained by the condensation of pyridine-2-carboxaldehyde and longer aromatic diamines like 44' diamino diphenyl, 44' diamino diphenyl methane and 44' diamino diphenyl ether respectively. These complexes have been characterised by elemental analysis, spectral, magnetic, electrochemical and FAB mass spectral studies. These complexes have been used as catalyst for the epoxidation of olefin using iodosyl benzene as oxidant. The combined effect of light and catalyst on the catalytic activity have also been investigated. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s1381-1169(97)00199-4