trans-chloro(trifluoromethanesulfonato)(bis(triisopropylphosphine))platinum(II) | 199920-88-2

• 英文名称: trans-chloro(trifluoromethanesulfonato)(bis(triisopropylphosphine))platinum(II)
• CAS: 199920-88-2
• 化学式: C₁₉H₄₂ClF₃O₃P₂PtS
• 分子量: 700.082
• InChiKey: YLCVCESLMHQVCD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-chloro(trifluoromethanesulfonato)(bis(triisopropylphosphine))platinum(II) 、 (triisopropylphosphine)(chloro)(2,2-diisopropyl-3-methyl-1-platina-2-phospha-cyclobutane) 以 二氯甲烷-D2 为溶剂， 生成 trans-dichlorobis(tri-isopropylphosphine)platinum(II) 、 (triisopropylphosphine)(trifluoromethanesulfonato)(2,2-diisopropyl-3-methyl-1-platina-2-phosphacyclobutane)
  参考文献：
  名称：

  Ligand Metalation in Triisopropylphosphine−Platinum(II) Compounds

  摘要：

  The compound trans-(methyl)(trifluoromethanesulfonato)(bis(triisopropylphosphine))-platinum(II) (1) is stable in solution at room temperature, but when treated with a catalytic amount of HCl, it undergoes rapid loss of methane and forms the metalated compound (triisopropylphosphine)(trifluoromethanesulfonato)(2,2-diisopropyl-3-methyl-1-platina-2-phosphacyclobutane) (2). The key intermediate is trans-chloro(trifluoromethanesulfonato)(bis-triisopropylphosphine))platinum(II) (3), which rapidly undergoes metalation with loss of trifluoromethanesulfonic acid.

  DOI：

  10.1021/om970759s