(5,7,7,13-tetramethyl-13-nitro-1,4,8,11-tetraaza-cyclotetradec-4-ene)copper(II) tetrachlorozincate | 885462-24-8

• 英文名称: (5,7,7,13-tetramethyl-13-nitro-1,4,8,11-tetraaza-cyclotetradec-4-ene)copper(II) tetrachlorozincate
• CAS: 885462-24-8
• 化学式: C₁₄H₂₉CuN₅O₂*Cl₄Zn
• 分子量: 570.165
• InChiKey: QITMJANUAVSAOO-XHCYYKEJSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (5,7,7,13-tetramethyl-13-nitro-1,4,8,11-tetraaza-cyclotetradec-4-ene)copper(II) perchlorate 、 zinc(II) chloride 以 异丙醇 、 乙腈 为溶剂， 生成 (5,7,7,13-tetramethyl-13-nitro-1,4,8,11-tetraaza-cyclotetradec-4-ene)copper(II) tetrachlorozincate
  参考文献：
  名称：

  Copper(II) compounds of some nitro-substituted imine-triamine macrocycles: The structure of (aqua κ1-O)-(13-ethyl-5,7,7-trimethyl-13-nitro-1,4,8,11-tetraazacyclotetradec-4-ene κ4-N1,4,8,11)copper(II) perchlorate

  摘要：

  Reactions of (4,6,6-trimethyl-3,7-diazanon-3-ene-1,9-diamine)copper(II) perchlorate with methanal and nitroethane (or nitropropane) yield the nitro-substituted imine-triamine azarnacrocyclic compounds (5,7,7,13 -tetramethyl- 13 -nitro- 1,4,8, 11 -tetraazacyclotetradec-4-ene)copper(II) [or (13-ethyl-5,7,7-trimethyl-13-nitro-1,4,8,11-tetraazacyclotetradec-4-ene)copper(II) perchlorate. Compounds of these cations [Cu(L)(ClO4)(2), -ZnCl4, [Cu(L)(A)](ClO4)(2), A = H2O, NH3 and [Cu(L)(X)]ClO4, X = NCS-, N-3(-), NO2-, were prepared. Aqua-(13-ethyl- 5,7,7-trimethyl-13-nitro-1,4,8,11-tetraazacyclotetradec-4-ene)copper(II) perchlorate has the copper(II) ion in tetrahedrally twisted (+/- 0.045(2) angstrom} square-planar coordination, with mean Cu-N-amine, = 2.019(4) angstrom and Cu-Ni in, = 1.918(2) angstrom. Oxygen of water {Cu-O = 2.279(2) angstrom} and perchlorate {Cu-O = 2.905(2) angstrom} occupy the axial sites, with the Cu displaced by 0.143(1) angstrom from the N-4 mean plane towards the water molecule. The cation has the IR,8S,11S configuration, with the nitro substituent and one of the gem methyl substituents axially oriented to the side of the CuN4 plane away from the water molecule. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.08.037