[N(2,6-iPr2C6H3)C(Ph)CHC(tBu)NH]2Co2(μ-Cl)3Li(THF)2 | 1300725-99-8

• 英文名称: [N(2,6-iPr2C6H3)C(Ph)CHC(tBu)NH]2Co2(μ-Cl)3Li(THF)2
• CAS: 1300725-99-8
• 化学式: C₅₈H₈₂Cl₃Co₂LiN₄O₂
• 分子量: 1098.6
• InChiKey: KFVYHMDKFULDNG-AWVHCHDJSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [N(2,6-iPr2C6H3)C(Ph)CHC(tBu)NH]2Co2(μ-Cl)3Li(THF)2 以 甲苯 为溶剂， 以82%的产率得到[N(2,6-iPr2C6H3)C(Ph)CHC(tBu)NH]2Co
  参考文献：
  名称：

  β-Diketiminato 3d-metal compounds: Synthesis, characterization and catalytic behavior towards ethylene

  摘要：

  The lithium beta-diketiminate (1c, [Li{N(2,6-(Pr2C6H3)-Pr-i)C(Ph)CHC(Bu-t)NH}](2) represented as (LiL)(2)) reacted with 3d-metal (II) chlorides to afford the corresponding compounds (2-7). All metal compounds were fully characterized by elemental, spectroscopic analyses and the single-crystal X-ray diffraction. The coordination geometries around the metals are shown to be tetrahedral within the trinuclear Co2Li compound (2), planar in ML2 (M = Co, 3), pseudo-tetrahedral conformation in the ML2 withMasMn (4), Fe (5) or Zn (6), and square planar in the dinickel compound (7). Indicated by the trimetallic Co2Li compound 2, a six-membered ring is constructed of three metal atoms and three bridged chlorides as a twisted conformation. An inversion center is present in the centroid of the Ni2Cl2 four-membered ring within compound 7. The plausible mechanism of forming ML2 was proposed through the chloro-bridged multinuclear compounds on the basis of isolated intermediates of trinuclear (2) and dinuclearic (7) compounds. Upon treatment with methylaluminoxane (MAO), the nickel compound 7 possessed good activity towards ethylene oligomerization, whereas the other metal compounds showed moderate activities towards ethylene polymerization. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.063
• 作为产物：
  描述：

  四氢呋喃 、 [N(2,6-iPr2C6H3)C(Ph)CHC(tBu)NHLi]2 、 cobalt(II) chloride 以 四氢呋喃 为溶剂， 以42%的产率得到[N(2,6-iPr2C6H3)C(Ph)CHC(tBu)NH]2Co2(μ-Cl)3Li(THF)2
  参考文献：
  名称：

  β-Diketiminato 3d-metal compounds: Synthesis, characterization and catalytic behavior towards ethylene

  摘要：

  The lithium beta-diketiminate (1c, [Li{N(2,6-(Pr2C6H3)-Pr-i)C(Ph)CHC(Bu-t)NH}](2) represented as (LiL)(2)) reacted with 3d-metal (II) chlorides to afford the corresponding compounds (2-7). All metal compounds were fully characterized by elemental, spectroscopic analyses and the single-crystal X-ray diffraction. The coordination geometries around the metals are shown to be tetrahedral within the trinuclear Co2Li compound (2), planar in ML2 (M = Co, 3), pseudo-tetrahedral conformation in the ML2 withMasMn (4), Fe (5) or Zn (6), and square planar in the dinickel compound (7). Indicated by the trimetallic Co2Li compound 2, a six-membered ring is constructed of three metal atoms and three bridged chlorides as a twisted conformation. An inversion center is present in the centroid of the Ni2Cl2 four-membered ring within compound 7. The plausible mechanism of forming ML2 was proposed through the chloro-bridged multinuclear compounds on the basis of isolated intermediates of trinuclear (2) and dinuclearic (7) compounds. Upon treatment with methylaluminoxane (MAO), the nickel compound 7 possessed good activity towards ethylene oligomerization, whereas the other metal compounds showed moderate activities towards ethylene polymerization. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.01.063