[ZnCl2(4-(3-pyridinyl)-1,2,4-triazole)]n | 1374996-61-8

• 英文名称: [ZnCl2(4-(3-pyridinyl)-1,2,4-triazole)]n
• CAS: 1374996-61-8
• 化学式: C₇H₆Cl₂N₄Zn
• 分子量: 282.447
• InChiKey: TXEMQDCHTGKJLB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [ZnCl2(4-(3-pyridinyl)-1,2,4-triazole)]n 、 sodium perchlorate 以 水 、 乙腈 为溶剂， 生成 [Zn3(4-(3-pyridinyl)-1,2,4-triazole)6(H2O)6](ClO4)6
  参考文献：
  名称：

  Various structures from 1D to trinuclear by anion-induced conversion

  摘要：

  Reaction of ZnCl2 or ZnBr2 with 4-(3-pyridinyl)-1,2,4-triazole (pytrz) yields two novel 1D coordination polymers, [Zn(pytrz)Cl-2](n) (1) and [Zn(pytrz)Br-2](n) (2). Their crystal structures have been determined using X-ray single crystal diffraction analysis. Their subsequent reactions with additional NaClO4 resulted in a re-assembled molecular structure, [Zn-3(pytrz)(6)(H2O)(6)](ClO4)(3) (3), featuring a linear trinuclear complex. In this work, conversion from 1D to 0D triggered by anion-induce have been achieved based on pytrz. ClO4 anions may act as the templates during the re-assembly and all of the three complexes exhibit strong blue fluorescence emission bands in the H2O solution at ambient temperature. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.01.048
• 作为产物：
  描述：

  4-(pyridin-3-yl)-4H-1,2,4-triazole 、 zinc(II) chloride 以 水 为溶剂， 以75%的产率得到[ZnCl2(4-(3-pyridinyl)-1,2,4-triazole)]n
  参考文献：
  名称：

  Various structures from 1D to trinuclear by anion-induced conversion

  摘要：

  Reaction of ZnCl2 or ZnBr2 with 4-(3-pyridinyl)-1,2,4-triazole (pytrz) yields two novel 1D coordination polymers, [Zn(pytrz)Cl-2](n) (1) and [Zn(pytrz)Br-2](n) (2). Their crystal structures have been determined using X-ray single crystal diffraction analysis. Their subsequent reactions with additional NaClO4 resulted in a re-assembled molecular structure, [Zn-3(pytrz)(6)(H2O)(6)](ClO4)(3) (3), featuring a linear trinuclear complex. In this work, conversion from 1D to 0D triggered by anion-induce have been achieved based on pytrz. ClO4 anions may act as the templates during the re-assembly and all of the three complexes exhibit strong blue fluorescence emission bands in the H2O solution at ambient temperature. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.01.048