| 1417705-41-9

• CAS: 1417705-41-9
• 化学式: CF₃O₃S*C₂₉H₃₁NPPd
• 分子量: 680.036
• InChiKey: MHAGVROFQRNFJE-PDSMNNBSSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-氯环戊烯-1-甲醛 在 activated 4 Å molecular sieves 作用下， 以 乙醚 、 二氯甲烷 、 正戊烷 为溶剂， 反应 127.0h， 生成
  参考文献：
  名称：

  Investigation of Steric and Electronic Features of 3-Iminophosphine-Based Palladium Catalysts for Intermolecular Hydroamination

  摘要：

  A series of (3-iminophosphine)allylpalladium triflate complexes with systematic variation of both steric and electronic features was isolated and characterized. The ability of the complexes in this series to catalyze the regioselective hydroamination of 3-methyl-1,2-butadiene with aryl amines to form solely the kinetic product was probed by observing conversion to products via NMR spectroscopy. The previously unstudied 3-iminophosphine ligand composed of a di-tert-butyl phosphine, cyclobutene backbone, and tert-butyl imine provided the most active palladium hydroamination catalyst for this transformation known to date.

  DOI：

  10.1021/om301102w