| 157205-01-1

• CAS: 157205-01-1
• 化学式: C₇H₁₁ClF₈N₂P₄Ru
• 分子量: 535.583
• InChiKey: HJIIZEFAUWJTMA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 H₂O 作用下， 以 二氯甲烷 为溶剂， 以80%的产率得到(eta.5-C5H5)Ru[P(O)F2][CH3NHPF2]2
  参考文献：
  名称：

  含甲基氨基双（二氟膦）的and和钌的异双金属配合物

  摘要：

  The syntheses of cpRuCl(eta1-MeN(PF2)2)2 (1) and fac-ReBr(CO)3(eta1-MeN(PF2)2)2 (3) are described together with their use in the directed synthesis of heterobimetallic complexes. The monodentate MeN(PF2)2 ligands in 1 are cleaved on exposure to moisture or on chromatography on Florisil to give cpRu(P(O)F2)(PF2NHMe)2 (2). With CO2(CO)8 1 and 3 respectively yield cpRu(mu-MeN(PF2)2)2Co(CO)2 (4) and fac-Re(CO)3(mu-MeN(PF2)2)2Co(CO)2 (5), while with IrCl(CO)(PPh3)2, cpRu(mu-MeN(PF2)2)2IrCl2(PPh3) (6) and fac-Re(CO)3(mu-MeN-(PF2)2)2IrClBr(PPh3) (7) are obtained. Complex 1 and [RhCl(CO)2]2 yield cpRu(mu-MeN(PF2)2)2RhCl2 (8) which adds dimethylphenylphosphine to give cpRu(mu-MeN(PF2)2)2RhCl2(PMe2Ph) (9) while with 3 the product is fac-Re(CO)3(mu-MeN(PF2)2)2RhClBr (10). A complex mixture of products is formed from 1 and Pt(L)(PPh3)2 (L = C2H4, C2Ph2) which has not been completely characterized, but fac-Re(CO)3(mu-MeN(PF2)2)2PtBr(PPh3) (11), in which the platinum adopts a distorted square pyramidal coordination with a very long apical Pt-Br bond, is obtained from 3 and Pt(C2Ph2)(PPh3)2. The structures of 2, 5, 9, and 11 have been determined by X-ray crystallography. 2: monoclinic; P2(1)/n; a = 10.487(2), b = 11.832(2), c = 11.910(2) angstrom; beta = 90.50(1)-degrees; Z = 4. 5: triclinic; P1BAR; a = 9.794(l), b = 10.563(l), c = 9.624(2) angstrom; alpha = 98.06(l), beta = 101.29(l), gamma = 81.796(9)-degrees; Z = 2. 9: monoclinic; P2(1)/c; a = 18.239(3), b = 8.195(2), c = 18.078(2) angstrom, beta = 102.36(l)-degrees; Z = 4. 11: monoclinic; C2/m; a = 12.649(2), b = 14.908(l), c = 19.798(2) angstrom; beta = 96.600(9)-degrees; Z = 4.

  DOI：

  10.1021/om00020a019
• 作为产物：
  描述：

  (η(5)-cyclopentadienyl)dicarbonylchlororuthenium(II) 、 bis(difluorophosphino)methylamine 以 正己烷 、 二氯甲烷 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  含甲基氨基双（二氟膦）的and和钌的异双金属配合物

  摘要：

  The syntheses of cpRuCl(eta1-MeN(PF2)2)2 (1) and fac-ReBr(CO)3(eta1-MeN(PF2)2)2 (3) are described together with their use in the directed synthesis of heterobimetallic complexes. The monodentate MeN(PF2)2 ligands in 1 are cleaved on exposure to moisture or on chromatography on Florisil to give cpRu(P(O)F2)(PF2NHMe)2 (2). With CO2(CO)8 1 and 3 respectively yield cpRu(mu-MeN(PF2)2)2Co(CO)2 (4) and fac-Re(CO)3(mu-MeN(PF2)2)2Co(CO)2 (5), while with IrCl(CO)(PPh3)2, cpRu(mu-MeN(PF2)2)2IrCl2(PPh3) (6) and fac-Re(CO)3(mu-MeN-(PF2)2)2IrClBr(PPh3) (7) are obtained. Complex 1 and [RhCl(CO)2]2 yield cpRu(mu-MeN(PF2)2)2RhCl2 (8) which adds dimethylphenylphosphine to give cpRu(mu-MeN(PF2)2)2RhCl2(PMe2Ph) (9) while with 3 the product is fac-Re(CO)3(mu-MeN(PF2)2)2RhClBr (10). A complex mixture of products is formed from 1 and Pt(L)(PPh3)2 (L = C2H4, C2Ph2) which has not been completely characterized, but fac-Re(CO)3(mu-MeN(PF2)2)2PtBr(PPh3) (11), in which the platinum adopts a distorted square pyramidal coordination with a very long apical Pt-Br bond, is obtained from 3 and Pt(C2Ph2)(PPh3)2. The structures of 2, 5, 9, and 11 have been determined by X-ray crystallography. 2: monoclinic; P2(1)/n; a = 10.487(2), b = 11.832(2), c = 11.910(2) angstrom; beta = 90.50(1)-degrees; Z = 4. 5: triclinic; P1BAR; a = 9.794(l), b = 10.563(l), c = 9.624(2) angstrom; alpha = 98.06(l), beta = 101.29(l), gamma = 81.796(9)-degrees; Z = 2. 9: monoclinic; P2(1)/c; a = 18.239(3), b = 8.195(2), c = 18.078(2) angstrom, beta = 102.36(l)-degrees; Z = 4. 11: monoclinic; C2/m; a = 12.649(2), b = 14.908(l), c = 19.798(2) angstrom; beta = 96.600(9)-degrees; Z = 4.

  DOI：

  10.1021/om00020a019