(C10H6CH(CH3)(NH2))PdCl(benzylcyclohexylphenylphosphine) | 244097-19-6

• 英文名称: (C10H6CH(CH3)(NH2))PdCl(benzylcyclohexylphenylphosphine)
• CAS: 244097-19-6
• 化学式: C₃₁H₃₅ClNPPd
• 分子量: 594.472
• InChiKey: DZMZUWNYHZILGC-RBKBCAOGSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,2-双(二苯基膦)乙烷 、 (2-methylallyl)palladium-chloride dimer 、 (C10H6CH(CH3)(NH2))PdCl(benzylcyclohexylphenylphosphine) 以 乙醚 为溶剂， 以85%的产率得到(SP)-[Pd(η(3)-2-MeC3H4)Cl(benzylcyclohexylphenylphosphine)]
  参考文献：
  名称：

  Resolution of Benzylcyclohexylphenylphosphine by Palladium(II)−Amine Metallacycles. A New Ligand for Asymmetric Hydrovinylation

  摘要：

  The synthesis of benzylcyclohexylphenylphosphine and its resolution by means of optically active palladium metallacycles are reported. The absolute configuration of (R-C,S-P)-[PdCl(C6H4CHMeNMe2)(PBzCyPh)] has been determined by single-crystal X-ray analyses. The allyl complex [Pd(eta(3)-2-MeC3H4)(PBzCyPh)S]BF4, prepared in situ from [Pd(eta(3)-2-MeC3H4)Cl(PBzCyPh)] and AgBF4 in CH2Cl2 solution, was used as a precatalyst for asymmetric hydrovinylatiom of styrene and 2-vinylnaphthalene. This system permits the synthesis of 3-phenyl-1-butene and 3-(2-naphthyl)-1-butene with good ee values working in very mild conditions of temperature (15 degrees C).

  DOI：

  10.1021/om990302d
• 作为产物：
  描述：

  benzylcyclohexylphenylphosphine 以 四氢呋喃 、 乙醇 为溶剂， 生成 (C10H6CH(CH3)(NH2))PdCl(benzylcyclohexylphenylphosphine)
  参考文献：
  名称：

  Resolution of Benzylcyclohexylphenylphosphine by Palladium(II)−Amine Metallacycles. A New Ligand for Asymmetric Hydrovinylation

  摘要：

  The synthesis of benzylcyclohexylphenylphosphine and its resolution by means of optically active palladium metallacycles are reported. The absolute configuration of (R-C,S-P)-[PdCl(C6H4CHMeNMe2)(PBzCyPh)] has been determined by single-crystal X-ray analyses. The allyl complex [Pd(eta(3)-2-MeC3H4)(PBzCyPh)S]BF4, prepared in situ from [Pd(eta(3)-2-MeC3H4)Cl(PBzCyPh)] and AgBF4 in CH2Cl2 solution, was used as a precatalyst for asymmetric hydrovinylatiom of styrene and 2-vinylnaphthalene. This system permits the synthesis of 3-phenyl-1-butene and 3-(2-naphthyl)-1-butene with good ee values working in very mild conditions of temperature (15 degrees C).

  DOI：

  10.1021/om990302d