[Co(η4-tetramethylcyclobutadiene)(η5-indenyl)] | 813420-36-9

• 英文名称: [Co(η4-tetramethylcyclobutadiene)(η5-indenyl)]
• 英文别名: [(tetramethylcyclobutadiene)Co(η5-indenyl)]；[(η4-C4Me4)Co(η5-indenyl)]
• CAS: 813420-36-9
• 化学式: C₁₇H₁₉Co
• 分子量: 282.331
• InChiKey: MXXOHBFCMXBUJS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate 、 [Co(η4-tetramethylcyclobutadiene)(η5-indenyl)] 以 硝基甲烷 为溶剂， 以79%的产率得到(μ,η5:η6-indenyl)[(η-pentamethylcyclopentadienyl)ruthenium][(η-tetramethylcyclobutadiene)cobalt]hexafluorophosphate
  参考文献：
  名称：

  Synthesis of slipped µ-indenyl triple-decker complexes containing (C4Me4)Co and (C5Me5)Ru fragments

  摘要：

  DOI：

  10.1007/s11172-005-0078-x
• 作为产物：
  描述：

  indenyllithium 、 [(η4-C4Me4)Co-(NCCH3)3]PF6 以 not given 为溶剂， 生成 [Co(η4-tetramethylcyclobutadiene)(η5-indenyl)]
  参考文献：
  名称：

  Synthesis of slipped µ-indenyl triple-decker complexes containing (C4Me4)Co and (C5Me5)Ru fragments

  摘要：

  DOI：

  10.1007/s11172-005-0078-x

文献信息

• (Tetramethylcyclobutadiene)cobalt Complexes with Five-Electron Carbo- and Heterocyclic Ligands
  作者：Elena V. Mutseneck、Dmitry A. Loginov、Dmitry S. Perekalin、Zoya A. Starikova、Denis G. Golovanov、Pavel V. Petrovskii、Piero Zanello、Maddalena Corsini、Franco Laschi、Alexander R. Kudinov

  DOI：10.1021/om0495832

  日期：2004.12.1

  g with NaBH4/AlCl3 or LiAlH4 affords the alkyl derivatives 5b and 5h (R = Et) or the alcohols 5i (R = CH2OH) and 5j (R = CH(OH)Me), respectively. The reaction of 1 with fluorene/AlCl3 yields complex [Cb*Co(η6-fluorene)]+ (8), which was deprotonated by KOBut to give Cb*Co(η6-fluorenyl) (9). Visible light irradiation of 9 induces η6→η5 haptotropic rearrangement to afford Cb*Co(η5-fluorenyl) (7). The pyrrolyl

  Tetramethylcyclobutadiene（环戊二烯基）钴络合物的Cb *钴（C 5 H ^ 4 R）（CB * =η 4 -C 4我4 ; R = H（图5a）中，Me（图5b），森达3（图5d），C（O） H（5f）和C（O）Me（5g））是通过环戊二烯阴离子与（羰基）碘化物络合物Cb * Co（CO）2 I（1）（方法A）或更高反应性的反应获得的乙腈络合物[Cb * Co（MeCN）3 ] +（2）（方法B）。类似化合物Cb * CoCp *（5c），Cb * Co（1,3-C5 ħ 3（森达3）2）（图5e），和Cb *钴（η 5 -茚基）（6）可以仅通过的方法B.处理来制备图5f，克用NaBH 4 /的AlCl 3或的LiAlH 4，得到烷基衍生物5b和5h（R = Et）或醇5i（R = CH 2 OH）和5j（R = CH（OH）Me）。的反应1与芴/的AlCl 3倍的产率络合物[*的Cb的Co（η
• Slipped μ‐Indenyl Triple‐Decker Complexes Containing (C ₄ Me ₄ )Co and (C ₅ R ₅ )Ru Fragments
  作者：Elena V. Mutseneck、Zoya A. Starikova、Konstantin A. Lyssenko、Pavel V. Petrovskii、Piero Zanello、Maddalena Corsini、Alexander R. Kudinov

  DOI：10.1002/ejic.200600264

  日期：2006.11

  AbstractSlipped triple‐decker complexes with a bridging indenyl ligand, namely [Cb*Co(μ:η5:η6‐C9H7)CoCb*]+ (2, Cb* = C4Me4) and [Cb*Co(μ:η5:η6‐C9H7)Ru(C5R5)]+ (R = H, 5a; Me, 5b), have been synthesised by electrophilic stacking of [Cb*Co(η5‐C9H7)] (1) with [Cb*Co(MeCN)3]+ or [(C5R5)Ru(MeCN)3]+ (R = H, Me), respectively. A similar reaction of [(C5R5)Ru(η5‐C9H7)] (R = H, 3a; Me, 3b) with [Cb*Co(MeCN)3]+ affords the cations [(C5R5)Ru(μ:η5:η6‐C9H7)CoCb*]+ (R = H, 4a; Me, 4b), which are isomeric with 5a,b. Stacking of [Ru(η5‐C9H7)2] (7) with [Cb*Co(MeCN)3]+ or [Cb*CoI]x/TlBF4 gives the triple‐decker complex [(η5‐C9H7)Ru(μ:η5:η6‐C9H7)CoCb*]+ (8). Further reaction of 8 with [Cp*RuCl]4/TlBF4 unexpectedly affords the slipped tetra‐decker ruthenium complex [Cp*Ru(μ:η5:η6‐C9H7)Ru(μ:η5:η6‐C9H7)RuCp*]2+ (11). The structures of [4b][Co(η‐7,8‐C2B9H11)2] and [Cp*Ru(η6‐C9H7)] (6) have been determined by X‐ray diffraction, and the electrochemical behaviour of the complexes prepared has been studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)